The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
High Proton Conductivity by a Metal–Organic Framework Incorporating Zn8O Clusters with Aligned Imidazolium Groups Decorating the Channels
Abstract
A novel metal-organic framework, [{(Zn(0.25))(8)(O)}Zn(6)(L)(12)(H(2)O)(29)(DMF)(69)(NO(3))(2)](n) (1) {H(2)L = 1,3-bis(4-carboxyphenyl)imidazolium}, has been synthesized under solvothermal conditions in good yield. It shows a Zn(8)O cluster that is coordinated to six ligands and forms an overall three-dimensional structure with channels along the crystallographic a and b axes. The imidazolium groups of the ligand moiety are aligned in the channels. The channels are not empty but are occupied by a large number of DMF and water molecules. Upon heating, these solvent molecules can be removed without breakdown of the overall structure of the framework as shown by variable-temperature powder X-ray diffraction patterns. Of great interest is the fact that the compound exhibits high proton conductivity with a low activation energy that is comparable to those of Nafion presently used in fuel cells.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Kreuer, K.-D., Paddison, S. J., Spohr, E., & Schuster, M. (2004) · Chemical Reviews · doi:10.1021/cr020715f · Cited by 2,187
Fang, Q.-R., Yuan, D.-Q., Sculley, J., Li, J.-R., Han, Z.-B., & Zhou, H.-C. (2010) · Inorganic Chemistry · doi:10.1021/ic101935f · Cited by 309
Promotion of Proton Conduction in Polymer Electrolyte Membranes by 1 H-1,2,3-Triazole
Zhou, Z., Li, S., Zhang, Y., Liu, M., & Li, W. (2005) · Journal of the American Chemical Society · doi:10.1021/ja052280u · Cited by 206
Cited by
Water Stability and Adsorption in Metal–Organic Frameworks
Burtch, N. C., Jasuja, H., & Walton, K. S. (2014) · Chemical Reviews · doi:10.1021/cr5002589 · Cited by 2,730
Water adsorption in MOFs: fundamentals and applications
Canivet, J., Fateeva, A., Guo, Y., Coasne, B., & Farrusseng, D. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00078a · Cited by 1,444
Metal–organic frameworks as platforms for clean energy
Li, S.-L., & Xu, Q. (2013) · Energy & Environmental Science · doi:10.1039/c3ee40507a · Cited by 970
Karmakar, A., Illathvalappil, R., Anothumakkool, B., Sen, A., Samanta, P., Desai, A. V., Kurungot, S., & Ghosh, S. K. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201604534 · Cited by 517
Li, W.-H., Deng, W.-H., Wang, G.-E., & Xu, G. (2020) · EnergyChem · doi:10.1016/j.enchem.2020.100029 · Cited by 373
Linker functionalized metal-organic frameworks
Ali Akbar Razavi, S., & Morsali, A. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2019.213023 · Cited by 341
Ionic metal-organic frameworks (iMOFs): Design principles and applications
Karmakar, A., Desai, A. V., & Ghosh, S. K. (2016) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2015.08.007 · Cited by 308
Metadata
- Authors
- Sen, S., Nair, N. N., Yamada, T., Kitagawa, H., & Bharadwaj, P. K.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-11-15
- Volume
- 134
- Issue
- 47
- Pages
- 19432-19437
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2320607859
- Cited by
- 280
- References
- 4
- FWCI
- 16.26
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
