Functional Mesoporous Metal−Organic Frameworks for the Capture of Heavy Metal Ions and Size-Selective Catalysis
Abstract
By using Zn(4)O(CO(2))(6) as secondary building units (SBUs) and two extended ligands containing amino functional groups, TATAB and BTATB (TATAB = 4,4',4''-s-triazine-1,3,5-triyltri-p-aminobenzoate and BTATB = 4,4',4''-(benzene-1,3,5-triyltris(azanediyl))tribenzoate), two isostructural mesoporous metal-organic frameworks (MOFs) with cavities up to 2.73 nm, designated as PCN-100 and PCN-101 (PCN represents porous coordination network), have been synthesized. N(2) sorption isotherms of both PCN-100 and -101 showed typical type IV behavior, indicating their mesoporous nature. The TATAB ligand that comprises PCN-100 was employed to capture heavy metal ions (Cd(II) and Hg(II)) by constructing complexes within the pores with a possible coordination mode similar to that found in aminopyridinato complexes. This reveals that mesoporous materials such as PCN-100 can be applied in the elimination of heavy metal ions from waste liquid. In addition, both PCNs-100 and -101 exhibit size-selective catalytic activity toward the Knoevenagel condensation reaction.
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Some reported MOFs used for ion-exchange reactions include AMOF-1 for Cd2+, Pb2+, and Hg2+ removal, ZIF-8 for Cu2+ removal, and ZIF-67 for Cr6+ removal.
“Some reported MOFs used for ion-exchange reactions include AMOF-1 (for Cd 2+ , Pb 2+ , and Hg 2+ removal 118 ), ZIF-8 (for Cu 2+ removal 119 ), and ZIF-67 (for Cr 6+ removal 120 ).”
From Removal of heavy metal ions from wastewater: a comprehensive and critical review (2021) · cites this paper as [118]
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Removal of heavy metal ions from wastewater: a comprehensive and critical review
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- Authors
- Fang, Q.-R., Yuan, D.-Q., Sculley, J., Li, J.-R., Han, Z.-B., & Zhou, H.-C.
- Affiliations
- Department of Chemistry, Texas A&M University, College Station, Texas 77842, United States
- Texas A&M University (US)
- Corresponding author
- Zhou, Hong-Cai
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-11-17
- Volume
- 49
- Issue
- 24
- Pages
- 11637-11642
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W2078582657
- Cited by
- 309
- References
- 41
- Citations by year
- 2026: 8 · 2025: 12 · 2024: 7 · 2023: 24 · 2022: 20 · 2021: 23 · 2020: 19 · 2019: 33 · 2018: 30 · 2017: 23 · 2016: 25 · 2015: 25 · 2014: 22 · 2013: 16 · 2012: 13
- FWCI
- 7.45
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Inorganic Chemistry (publishedVersion)
- PubMed (publishedVersion)
- Funders
- U.S. Department of Energy (DESC0001015)
- Division of Chemistry
- Topics
- Physical Sciences › Chemistry › Inorganic Chemistry › Metal-Organic Frameworks: Synthesis and Applications
- Physical Sciences › Materials Science › Materials Chemistry › Mesoporous Materials and Catalysis
- Physical Sciences › Materials Science › Materials Chemistry › Covalent Organic Framework Applications
- Keywords
- mesoporous metal-organic frameworks, cadmium, mercury, size-selective catalysis, Knoevenagel condensation, wastewater remediation, isostructural MOFs
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