The DOI matches its Crossref record.
Monoplatinum Doping of Gold Nanoclusters and Catalytic Application
Abstract
We report single-atom doping of gold nanoclusters (NCs), and its drastic effects on the optical, electronic, and catalytic properties, using the 25-atom system as a model. In our synthetic approach, a mixture of Pt(1)Au(24)(SC(2)H(4)Ph)(18) and Au(25)(SC(2)H(4)Ph)(18) was produced via a size-focusing process, and then Pt(1)Au(24)(SC(2)H(4)Ph)(18) NCs were obtained by selective decomposition of Au(25)(SC(2)H(4)Ph)(18) in the mixture with concentrated H(2)O(2) followed by purification via size-exclusion chromatography. Experimental and theoretical analyses confirmed that Pt(1)Au(24)(SC(2)H(4)Ph)(18) possesses a Pt-centered icosahedral core capped by six Au(2)(SC(2)H(4)Ph)(3) staples. The Pt(1)Au(24)(SC(2)H(4)Ph)(18) cluster exhibits greatly enhanced stability and catalytic activity relative to Au(25)(SC(2)H(4)Ph)(18) but a smaller energy gap (E(g) ≈ 0.8 eV vs 1.3 eV for the homogold cluster).
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles
Liu, L., & Corma, A. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00776 · Cited by 4,777
All-thiol-stabilized Ag44 and Au12Ag32 nanoparticles with single-crystal structures
Yang, H., Wang, Y., Huang, H., Gell, L., Lehtovaara, L., Malola, S., Häkkinen, H., & Zheng, N. (2013) · Nature Communications · doi:10.1038/ncomms3422 · Cited by 786
Atomically precise copper nanoclusters and their applications
Liu, X., & Astruc, D. (2018) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2018.01.001 · Cited by 322
The role and fate of capping ligands in colloidally prepared metal nanoparticle catalysts
Rossi, L. M., Fiorio, J. L., Garcia, M. A. S., & Ferraz, C. P. (2018) · Dalton Transactions · doi:10.1039/c7dt04728b · Cited by 284
Sun, M., Ji, J., Hu, M., Weng, M., Zhang, Y., Yu, H., Tang, J., Zheng, J., Jiang, Z., Pan, F., et al. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b02305 · Cited by 100
Metadata
- Authors
- Qian, H., Jiang, D.-E., Li, G., Gayathri, C., Das, A., Gil, R. R., & Jin, R.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-09-19
- Volume
- 134
- Issue
- 39
- Pages
- 16159-16162
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2081185606
- Cited by
- 500
- References
- 0
- FWCI
- 17.09
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Monoplatinum Doping of Gold Nanoclusters and Catalytic Application. https://app.cochat.ai/papers/10.1021/ja307657a
- The paper
- Qian, H., Jiang, D.-E., Li, G., Gayathri, C., Das, A., Gil, R. R., & Jin, R. (2012). Monoplatinum Doping of Gold Nanoclusters and Catalytic Application. Journal of the American Chemical Society. https://doi.org/10.1021/ja307657a
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
