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Artificial Z-Scheme Constructed with a Supramolecular Metal Complex and Semiconductor for the Photocatalytic Reduction of CO2
Open accessAbstract
A hybrid for the visible-light-driven photocatalytic reduction of CO2 using methanol as a reducing agent was developed by combining two different types of photocatalysts: a Ru(II) dinuclear complex (RuBLRu') used for CO2 reduction is adsorbed onto Ag-loaded TaON (Ag/TaON) for methanol oxidation. Isotope experiments clearly showed that this hybrid photocatalyst mainly produced HCOOH (TN = 41 for 9 h irradiation) from CO2 and HCHO from methanol. Therefore, it converted light energy into chemical energy (ΔG° = +83.0 kJ/mol). Photocatalytic reaction proceeds by the stepwise excitation of Ag/TaON and the Ru dinuclear complex on Ag/TaON, similar to the photosynthesis Z-scheme.
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Cited by
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Kuriki, R., Matsunaga, H., Nakashima, T., Wada, K., Yamakata, A., Ishitani, O., & Maeda, K. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b01997 · Cited by 482
Self-citationPhotochemical Reduction of CO2 by Graphitic Carbon Nitride Polymers
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Huo, Y., Zhang, J., Dai, K., Li, Q., Lv, J., Zhu, G., & Liang, C. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2018.09.073 · Cited by 394
Reaction mechanisms of catalytic photochemical CO2 reduction using Re(I) and Ru(II) complexes
Kuramochi, Y., Ishitani, O., & Ishida, H. (2018) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.11.023 · Cited by 325
Self-citationSupramolecular Photocatalysts for the Reduction of CO2
Tamaki, Y., & Ishitani, O. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b00440 · Cited by 282
Self-citationKuriki, R., Yamamoto, M., Higuchi, K., Yamamoto, Y., Akatsuka, M., Lu, D., Yagi, S., Yoshida, T., Ishitani, O., & Maeda, K. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201701627 · Cited by 258
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Metadata
- Authors
- Sekizawa, K., Maeda, K., Domen, K., Koike, K., & Ishitani, O.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-03-13
- Volume
- 135
- Issue
- 12
- Pages
- 4596-4599
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2142622397
- Cited by
- 445
- References
- 0
- FWCI
- 16.95
- Type
- journal article
- Language
- en
- Open access
- hybrid
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