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Cited by 252

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Striped, Ellipsoidal Particles by Controlled Assembly of Diblock Copolymers

Jang, Se Gyu, Audus, Debra J., Klinger, Daniel, Krogstad, Daniel V., Kim, Bumjoon J., Cameron, Alexandre, Kim, Sang-Woo, Delaney, Kris T., Hur, Su-Mi, Killops, Kato L., Fredrickson, Glenn H., Kramer, Edward J., Hawker, Craig J.·2013·Journal of the American Chemical Society

Abstract

Control of interfacial interactions leads to a dramatic change in shape and morphology for particles based on poly(styrene-b-2-vinylpyridine) diblock copolymers. Key to these changes is the addition of Au-based surfactant nanoparticles (SNPs) which are adsorbed at the interface between block copolymer-containing emulsion droplets and the surrounding amphiphilic surfactant to afford asymmetric, ellipsoid particles. The mechanism of formation for these novel nanostructures was investigated by systematically varying the volume fraction of SNPs, with the results showing the critical nature that the segregation of SNPs to specific interfaces plays in controlling structure. A theoretical description of the system allows the size distribution and aspect ratio of the asymmetric block copolymer colloidal particles to be correlated with the experimental results.

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Metadata

Authors
Jang, S. G., Audus, D. J., Klinger, D., Krogstad, D. V., Kim, B. J., Cameron, A., Kim, S.-W., Delaney, K. T., Hur, S.-M., Killops, K. L., Fredrickson, G. H., Kramer, E. J., & Hawker, C. J.
Venue
Journal of the American Chemical Society
Published
2013-04-17
Volume
135
Issue
17
Pages
6649-6657
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2021518179
Cited by
252
References
0
FWCI
10.06
Type
journal article
Language
en
Open access
closed

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