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Long-Chain Terminal Alcohols through Catalytic CO Hydrogenation
Abstract
We show that long-chain 1-alcohols can be produced with high selectivities using heterogeneous CO hydrogenation catalysis. This breakthrough is achieved through the targeted design of "CoCuMn" nanosized core-shell particles using co-precipitation of metal salts into oxalate precursors and subsequent thermal decomposition. Using stoichiometric CO/H2 feeds, the selectivities to 1-alcohols or combined 1-alcohols/1-alkenes are usually higher than 60% and occasionally up to 95%. The Anderson-Schulz-Flory chain-lengthening probabilities for these products are higher than 0.6, but usually below 0.9 so as to optimize the C8-C14 slate as feedstock for plasticizers, lubricants, or detergents.
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Cited by
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Jiang, K., Back, S., Akey, A. J., Xia, C., Hu, Y., Liang, W., Schaak, D., Stavitski, E., Nørskov, J. K., Siahrostami, S., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-11992-2 · Cited by 820
Status and prospects in higher alcohols synthesis from syngas
Luk, H. T., Mondelli, C., Ferré, D. C., Stewart, J. A., & Pérez-Ramírez, J. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00324a · Cited by 745
The recent development of efficient Earth-abundant transition-metal nanocatalysts
Wang, D., & Astruc, D. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00629a · Cited by 608
Sun, Q., Dai, Z., Liu, X., Sheng, N., Deng, F., Meng, X., & Xiao, F.-S. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b02122 · Cited by 373
Active Centers of Catalysts for Higher Alcohol Synthesis from Syngas: A Review
Ao, M., Pham, G. H., Sunarso, J., Tade, M. O., & Liu, S. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b01391 · Cited by 320
Metadata
- Authors
- Xiang, Y., Chitry, V., Liddicoat, P., Felfer, P., Cairney, J., Ringer, S., & Kruse, N.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-05-06
- Volume
- 135
- Issue
- 19
- Pages
- 7114-7117
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1974261797
- Cited by
- 195
- References
- 0
- FWCI
- 7.12
- Type
- journal article
- Language
- en
- Open access
- closed
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- Xiang, Y., Chitry, V., Liddicoat, P., Felfer, P., Cairney, J., Ringer, S., & Kruse, N. (2013). Long-Chain Terminal Alcohols through Catalytic CO Hydrogenation. Journal of the American Chemical Society. https://doi.org/10.1021/ja402512r
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