The DOI matches its Crossref record; 68 of the 68 references it cites were found in a registry or an index.
Highly selective oxygen reduction to hydrogen peroxide on transition metal single atom coordination
Open accessAbstract
Shifting electrochemical oxygen reduction towards 2e– pathway to hydrogen peroxide (H 2 O 2), instead of the traditional 4e– to water, becomes increasingly important as a green method for H 2 O 2 generation. Here, through a flexible control of oxygen reduction pathways on different transition metal single atom coordination in carbon nanotube, we discovered Fe-C-O as an efficient H 2 O 2 catalyst, with an unprecedented onset of 0.822 V versus reversible hydrogen electrode in 0.1 M KOH to deliver 0.1 mA cm−2 H 2 O 2 current, and a high H 2 O 2 selectivity of above 95% in both alkaline and neutral pH. A wide range tuning of 2e–/4e– ORR pathways was achieved via different metal centers or neighboring metalloid coordination. Density functional theory calculations indicate that the Fe-C-O motifs, in a sharp contrast to the well-known Fe-C-N for 4e–, are responsible for the H 2 O 2 pathway. This iron single atom catalyst demonstrated an effective water disinfection as a representative application.
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Cation‐Vacancy‐Enriched Nickel Phosphide for Efficient Electrosynthesis of Hydrogen Peroxides
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Metadata
- Authors
- Jiang, K., Back, S., Akey, A. J., Xia, C., Hu, Y., Liang, W., Schaak, D., Stavitski, E., Nørskov, J. K., Siahrostami, S., & Wang, H.
- Venue
- Nature Communications
- Published
- 2019-09-05
- Volume
- 10
- Issue
- 1
- Pages
- 3997-3997
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2971471509
- Cited by
- 820
- References
- 68
- FWCI
- 18.29
- Type
- journal article
- Language
- en
- Open access
- gold
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- Jiang, K., Back, S., Akey, A. J., Xia, C., Hu, Y., Liang, W., Schaak, D., Stavitski, E., Nørskov, J. K., Siahrostami, S., & Wang, H. (2019). Highly selective oxygen reduction to hydrogen peroxide on transition metal single atom coordination. Nature Communications. https://doi.org/10.1038/s41467-019-11992-2
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