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Heterogenization of Homogeneous Catalysts in Metal–Organic Frameworks via Cation Exchange
Abstract
This paper describes the heterogenization of single-site transition-metal catalysts in metal-organic frameworks (MOFs) via cation exchange. A variety of cationic complexes of Pd, Fe, Ir, Rh, and Ru have been incorporated into ZJU-28, and the new materials have been characterized by optical microscopy, inductively coupled plasma optical emission spectroscopy, and powder X-ray diffraction. MOF-supported [Rh(dppe)(COD)]BF4 catalyzes the hydrogenation of 1-octene to n-octane. The activity of this supported catalyst compares favorably to its homogeneous counterpart, and it can be recycled at least four times. Overall, this work provides a new and general approach for supporting transition-metal catalysts in MOFs.
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Citations
Cites
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Cited by
Bridging homogeneous and heterogeneous catalysis by heterogeneous single-metal-site catalysts
Cui, X., Li, W., Ryabchuk, P., Junge, K., & Beller, M. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0090-9 · Cited by 1,119
Single-Atom Catalysis toward Efficient CO2 Conversion to CO and Formate Products
Su, X., Yang, X.-F., Huang, Y., Liu, B., & Zhang, T. (2019) · Accounts of Chemical Research · doi:10.1021/acs.accounts.8b00478 · Cited by 499
MOF-enabled confinement and related effects for chemical catalyst presentation and utilization
Liu, J., Goetjen, T. A., Wang, Q., Knapp, J. G., Wasson, M. C., Yang, Y., Syed, Z. H., Delferro, M., Notestein, J. M., Farha, O. K., et al. (2022) · Chemical Society Reviews · doi:10.1039/d1cs00968k · Cited by 386
Single-Atom (Iron-Based) Catalysts: Synthesis and Applications
Singh, B., Gawande, M. B., Kute, A. D., Varma, R. S., Fornasiero, P., McNeice, P., Jagadeesh, R. V., Beller, M., & Zbořil, R. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00158 · Cited by 373
Manna, K., Zhang, T., & Lin, W. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5018267 · Cited by 313
Metadata
- Authors
- Genna, D. T., Wong-Foy, A. G., Matzger, A. J., & Sanford, M. S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-07-09
- Volume
- 135
- Issue
- 29
- Pages
- 10586-10589
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2064311631
- Cited by
- 299
- References
- 1
- FWCI
- 16.97
- Type
- journal article
- Language
- en
- Open access
- closed
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- Genna, D. T., Wong-Foy, A. G., Matzger, A. J., & Sanford, M. S. (2013). Heterogenization of Homogeneous Catalysts in Metal–Organic Frameworks via Cation Exchange. Journal of the American Chemical Society. https://doi.org/10.1021/ja402577s
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