The DOI matches its Crossref record; 30 of the 30 references it cites were found in a registry or an index.
Postsynthetic Metalation of Bipyridyl-Containing Metal–Organic Frameworks for Highly Efficient Catalytic Organic Transformations
Abstract
We have designed highly stable and recyclable single-site solid catalysts via postsynthetic metalation of the 2,2'-bipyridyl-derived metal-organic framework (MOF) of the UiO structure (bpy-UiO). The Ir-functionalized MOF (bpy-UiO-Ir) is a highly active catalyst for both borylation of aromatic C-H bonds using B2(pin)2 (pin = pinacolate) and ortho-silylation of benzylicsilyl ethers; the ortho-silylation activity of the bpy-UiO-Ir is at least 3 orders of magnitude higher than that of the homogeneous control. The Pd-functionalized MOF (bpy-UiO-Pd) catalyzes the dehydrogenation of substituted cyclohexenones to afford phenol derivatives with oxygen as the oxidant. Most impressively, the bpy-UiO-Ir was recycled and reused 20 times for the borylation reaction without loss of catalytic activity or MOF crystallinity. This work highlights the opportunity in designing highly stable and active catalysts based on MOFs containing nitrogen donor ligands for important organic transformations.
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Covalent Chemistry beyond Molecules
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Bioinspired Metal–Organic Framework Catalysts for Selective Methane Oxidation to Methanol
Baek, J., Rungtaweevoranit, B., Pei, X., Park, M., Fakra, S. C., Liu, Y.-S., Matheu, R., Alshmimri, S. A., Alshehri, S., Trickett, C. A., et al. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b11525 · Cited by 417
MOF-enabled confinement and related effects for chemical catalyst presentation and utilization
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Luminescent rare-earth-based MOFs as optical sensors
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Metadata
- Authors
- Manna, K., Zhang, T., & Lin, W.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-04-23
- Volume
- 136
- Issue
- 18
- Pages
- 6566-6569
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2313371282
- Cited by
- 313
- References
- 30
- FWCI
- 19.61
- Type
- journal article
- Language
- en
- Open access
- closed
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