The DOI matches its Crossref record; 33 of the 33 references it cites were found in a registry or an index.
Boosting the Ambipolar Performance of Solution-Processable Polymer Semiconductors via Hybrid Side-Chain Engineering
Abstract
Ambipolar polymer semiconductors are highly suited for use in flexible, printable, and large-area electronics as they exhibit both n-type (electron-transporting) and p-type (hole-transporting) operations within a single layer. This allows for cost-effective fabrication of complementary circuits with high noise immunity and operational stability. Currently, the performance of ambipolar polymer semiconductors lags behind that of their unipolar counterparts. Here, we report on the side-chain engineering of conjugated, alternating electron donor-acceptor (D-A) polymers using diketopyrrolopyrrole-selenophene copolymers with hybrid siloxane-solubilizing groups (PTDPPSe-Si) to enhance ambipolar performance. The alkyl spacer length of the hybrid side chains was systematically tuned to boost ambipolar performance. The optimized three-dimensional (3-D) charge transport of PTDPPSe-Si with pentyl spacers yielded unprecedentedly high hole and electron mobilities of 8.84 and 4.34 cm(2) V(-1) s(-1), respectively. These results provide guidelines for the molecular design of semiconducting polymers with hybrid side chains.
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Cites
Charge Transport in Organic Semiconductors
Coropceanu, V., Cornil, J., da Silva Filho, D. A., Olivier, Y., Silbey, R., & Brédas, J.-L. (2007) · Chemical Reviews · doi:10.1021/cr050140x · Cited by 4,607
Polymer–Fullerene Composite Solar Cells
Thompson, B. C., & Fréchet, J. M. J. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200702506 · Cited by 4,150
A high-mobility electron-transporting polymer for printed transistors
Yan, H., Chen, Z., Zheng, Y., Newman, C., Quinn, J. R., Dötz, F., Kastler, M., & Facchetti, A. (2009) · Nature · doi:10.1038/nature07727 · Cited by 3,009
General observation of n-type field-effect behaviour in organic semiconductors
Chua, L.-L., Zaumseil, J., Chang, J.-F., Ou, E. C.-W., Ho, P. K.-H., Sirringhaus, H., & Friend, R. H. (2005) · Nature · doi:10.1038/nature03376 · Cited by 2,264
Liquid-crystalline semiconducting polymers with high charge-carrier mobility
McCulloch, I., Heeney, M., Bailey, C., Genevicius, K., MacDonald, I., Shkunov, M., Sparrowe, D., Tierney, S., Wagner, R., Zhang, W., et al. (2006) · Nature Materials · doi:10.1038/nmat1612 · Cited by 2,151
Flexible active-matrix displays and shift registers based on solution-processed organic transistors
Gelinck, G. H., Huitema, H. E. A., van Veenendaal, E., Cantatore, E., Schrijnemakers, L., van der Putten, J. B. P. H., Geuns, T. C. T., Beenhakkers, M., Giesbers, J. B., Huisman, B.-H., et al. (2004) · Nature Materials · doi:10.1038/nmat1061 · Cited by 1,582
Ultralow-power organic complementary circuits
Klauk, H., Zschieschang, U., Pflaum, J., & Halik, M. (2007) · Nature · doi:10.1038/nature05533 · Cited by 1,398
Someya, T., Kato, Y., Sekitani, T., Iba, S., Noguchi, Y., Murase, Y., Kawaguchi, H., & Sakurai, T. (2005) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0502392102 · Cited by 1,389
Rogers, J. A., Bao, Z., Baldwin, K., Dodabalapur, A., Crone, B., Raju, V. R., Kuck, V., Katz, H., Amundson, K., Ewing, J., et al. (2001) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.091588098 · Cited by 1,117
Tuning charge transport in solution-sheared organic semiconductors using lattice strain
Giri, G., Verploegen, E., Mannsfeld, S. C. B., Atahan-Evrenk, S., Kim, D. H., Lee, S. Y., Becerril, H. A., Aspuru-Guzik, A., Toney, M. F., & Bao, Z. (2011) · Nature · doi:10.1038/nature10683 · Cited by 1,100
Cited by
Recent Progress in High‐Mobility Organic Transistors: A Reality Check
Paterson, A. F., Singh, S., Fallon, K. J., Hodsden, T., Han, Y., Schroeder, B. C., Bronstein, H., Heeney, M., McCulloch, I., & Anthopoulos, T. D. (2018) · Advanced Materials · doi:10.1002/adma.201801079 · Cited by 641
Kim, G., Kang, S.-J., Dutta, G. K., Han, Y.-K., Shin, T. J., Noh, Y.-Y., & Yang, C. (2014) · Journal of the American Chemical Society · doi:10.1021/ja504537v · Cited by 607
Self-citationInsight into High-Performance Conjugated Polymers for Organic Field-Effect Transistors
Yang, J., Zhao, Z., Wang, S., Guo, Y., & Liu, Y. (2018) · Chem · doi:10.1016/j.chempr.2018.08.005 · Cited by 462
Flexible Organic Electronics in Biology: Materials and Devices
Liao, C., Zhang, M., Yao, M. Y., Hua, T., Li, L., & Yan, F. (2015) · Advanced Materials · doi:10.1002/adma.201402625 · Cited by 438
Ashraf, R. S., Meager, I., Nikolka, M., Kirkus, M., Planells, M., Schroeder, B. C., Holliday, S., Hurhangee, M., Nielsen, C. B., Sirringhaus, H., et al. (2015) · Journal of the American Chemical Society · doi:10.1021/ja511984q · Cited by 417
Metadata
- Authors
- Lee, J., Han, A.-R., Yu, H., Shin, T. J., Yang, C., & Oh, J. H.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-06-13
- Volume
- 135
- Issue
- 25
- Pages
- 9540-9547
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2059106585
- Cited by
- 498
- References
- 33
- FWCI
- 42.54
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lee, J., Han, A.-R., Yu, H., Shin, T. J., Yang, C., & Oh, J. H. (2013). Boosting the Ambipolar Performance of Solution-Processable Polymer Semiconductors via Hybrid Side-Chain Engineering. Journal of the American Chemical Society. https://doi.org/10.1021/ja403949g
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