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Direct Catalytic Anti-Markovnikov Addition of Carboxylic Acids to Alkenes
Open accessAbstract
A direct catalytic anti-Markovnikov addition of carboxylic acids to alkenes is reported. The catalyst system is comprised of the Fukuzumi acridinium photooxidant (1) and a substoichiometric quantity of a hydrogen-atom donor. Oxidizable olefins, such as styrenes, trisubstituted aliphatic alkenes, and enamides, can be employed along with a variety of carboxylic acids to afford the anti-Markovnikov addition adducts exclusively. A deuterium-labeling experiment lends insight to the potential mechanism.
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Cited by
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Fernández-García, E. (2014) · Food & Function · doi:10.1039/c4fo00280f · Cited by 108
Metadata
- Authors
- Perkowski, A. J., & Nicewicz, D. A.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-07-03
- Volume
- 135
- Issue
- 28
- Pages
- 10334-10337
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2028208613
- Cited by
- 215
- References
- 0
- FWCI
- 9.94
- Type
- journal article
- Language
- en
- Open access
- green
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- CoChat. (2026). Citation check: Direct Catalytic Anti-Markovnikov Addition of Carboxylic Acids to Alkenes. https://app.cochat.ai/papers/10.1021/ja4057294
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- Perkowski, A. J., & Nicewicz, D. A. (2013). Direct Catalytic Anti-Markovnikov Addition of Carboxylic Acids to Alkenes. Journal of the American Chemical Society. https://doi.org/10.1021/ja4057294
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
