The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Hydrogen Evolution from Neutral Water under Aerobic Conditions Catalyzed by Cobalt Microperoxidase-11
Abstract
A molecular electrocatalyst is reported that reduces protons to hydrogen (H2) in neutral water under aerobic conditions. The biomolecular catalyst is made from cobalt substitution of microperoxidase-11, a water-soluble heme-undecapeptide derived from the protein horse cytochrome c. In aqueous solution at pH 7.0, the catalyst operates with near quantitative Faradaic efficiency, a turnover frequency ~6.7 s(-1) measured over 10 min at an overpotential of 852 mV, and a turnover number of 2.5 × 10(4). Catalyst activity has low sensitivity to oxygen. The results show promise as a hydrogenase functional mimic derived from a biomolecule.
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Citations
Cites
Identification of Active Edge Sites for Electrochemical H 2 Evolution from MoS 2 Nanocatalysts
Jaramillo, T. F., Jørgensen, K. P., Bonde, J., Nielsen, J. H., Horch, S., & Chorkendorff, I. (2007) · Science · doi:10.1126/science.1141483 · Cited by 6,100
Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
Popczun, E. J., McKone, J. R., Read, C. G., Biacchi, A. J., Wiltrout, A. M., Lewis, N. S., & Schaak, R. E. (2013) · Journal of the American Chemical Society · doi:10.1021/ja403440e · Cited by 2,911
Recent developments of molybdenum and tungsten sulfides as hydrogen evolution catalysts
Merki, D., & Hu, X. (2011) · Energy & Environmental Science · doi:10.1039/c1ee01970h · Cited by 1,172
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Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes
Dalle, K. E., Warnan, J., Leung, J. J., Reuillard, B., Karmel, I. S., & Reisner, E. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00392 · Cited by 912
Artificial Metalloenzymes: Reaction Scope and Optimization Strategies
Schwizer, F., Okamoto, Y., Heinisch, T., Gu, Y., Pellizzoni, M. M., Lebrun, V., Reuter, R., Köhler, V., Lewis, J. C., & Ward, T. R. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00014 · Cited by 831
Anantharaj, S., & Aravindan, V. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201902666 · Cited by 361
Nickel Complexes for Robust Light-Driven and Electrocatalytic Hydrogen Production from Water
Das, A., Han, Z., Brennessel, W. W., Holland, P. L., & Eisenberg, R. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00045 · Cited by 258
Metadata
- Authors
- Kleingardner, J. G., Kandemir, B., & Bren, K. L.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-12-23
- Volume
- 136
- Issue
- 1
- Pages
- 4-7
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2315816411
- Cited by
- 210
- References
- 3
- FWCI
- 6.01
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kleingardner, J. G., Kandemir, B., & Bren, K. L. (2014). Hydrogen Evolution from Neutral Water under Aerobic Conditions Catalyzed by Cobalt Microperoxidase-11. Journal of the American Chemical Society. https://doi.org/10.1021/ja406818h
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