The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
A Bio-Inspired, Small Molecule Electron-Coupled-Proton Buffer for Decoupling the Half-Reactions of Electrolytic Water Splitting
Abstract
Electron-coupled-proton buffers (ECPBs) allow H2 and O2 evolution to be separated from each other in time during the electrolysis of water. Natural photosynthetic systems achieve an analogous feat during water splitting and employ a range of intermediate redox mediators such as quinone derivatives to aid this process. Drawing on this natural example, we show that a low molecular weight quinone derivative is capable of decoupling H2 evolution from O2 evolution at scale during electrochemical water splitting. This work could significantly lower the cost of ECPBs, paving the way for their more widespread adoption in water splitting.
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Citations
Cites
Semiconductor-based Photocatalytic Hydrogen Generation
Chen, X., Shen, S., Guo, L., & Mao, S. S. (2010) · Chemical Reviews · doi:10.1021/cr1001645 · Cited by 7,876
Comparing Photosynthetic and Photovoltaic Efficiencies and Recognizing the Potential for Improvement
Blankenship, R. E., Tiede, D. M., Barber, J., Brudvig, G. W., Fleming, G., Ghirardi, M., Gunner, M. R., Junge, W., Kramer, D. M., Melis, A., et al. (2011) · Science · doi:10.1126/science.1200165 · Cited by 1,638
Cited by
Earth-abundant catalysts for electrochemical and photoelectrochemical water splitting
Roger, I., Shipman, M. A., & Symes, M. D. (2017) · Nature Reviews Chemistry · doi:10.1038/s41570-016-0003 · Cited by 3,503
Self-citationBifunctional Electrocatalysts for Overall and Hybrid Water Splitting
Quan, L., Jiang, H., Mei, G., Sun, Y., & You, B. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00332 · Cited by 874
Rausch, B., Symes, M. D., Chisholm, G., & Cronin, L. (2014) · Science · doi:10.1126/science.1257443 · Cited by 770
Self-citationWater Electrolysis toward Elevated Temperature: Advances, Challenges and Frontiers
Zhang, W., Liu, M., Gu, X., Shi, Y., Deng, Z., & Cai, N. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00573 · Cited by 441
Low-temperature water electrolysis: fundamentals, progress, and new strategies
Li, W., Tian, H., Ma, L., Wang, Y., Liu, X., & Gao, X. (2022) · Materials Advances · doi:10.1039/d2ma00185c · Cited by 312
Metadata
- Authors
- Rausch, B., Symes, M. D., & Cronin, L.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-09-06
- Volume
- 135
- Issue
- 37
- Pages
- 13656-13659
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2050282359
- Cited by
- 166
- References
- 2
- FWCI
- 2.28
- Type
- journal article
- Language
- en
- Open access
- closed
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