Decoupled catalytic hydrogen evolution from a molecular metal oxide redox mediator in water splitting

Rausch, Benjamin; Symes, Mark D.; Chisholm, Greig; Cronin, Leroy

doi:10.1126/science.1257443

Cited by 770

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Decoupled catalytic hydrogen evolution from a molecular metal oxide redox mediator in water splitting

Rausch, Benjamin, Symes, Mark D., Chisholm, Greig, Cronin, Leroy·2014·Science

DOI 10.1126/science.1257443

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Abstract

Scheduling hydrogen release from water: Photosynthesis splits water to provide protons and electrons for plant growth; oxygen is a by-product. When chemists split water, they're also more interested in making fuel, and the simplest product is hydrogen (a combination of protons and electrons). One challenge is keeping the reactive hydrogen and oxygen product streams separate. Rausch et al. present a scheme that captures the protons and electrons in a molecular cluster of silico-tungstic acid. Later, they expose the cluster to platinum, coaxing the acid into releasing hydrogen. Eliminating the mixing risk increases the potential for household use. Science , this issue p. 1326

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Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
Popczun, E. J., McKone, J. R., Read, C. G., Biacchi, A. J., Wiltrout, A. M., Lewis, N. S., & Schaak, R. E. (2013) · Journal of the American Chemical Society · doi:10.1021/ja403440e · Cited by 2,911

Show all 1 references

Research works printed but not linked: 39

10.1126/science.1179773 · DOI · Paper page
10.1002/cssc.201000182 · DOI · Paper page
10.1016/j.cattod.2008.08.039 · DOI · Paper page
10.1038/nchem.761 · DOI · Paper page
10.1021/ar900209b · DOI · Paper page
10.1016/j.ijhydene.2013.01.151 · DOI · Paper page
10.1038/nphoton.2012.175 · DOI · Paper page
10.1126/science.1209816 · DOI · Paper page
10.1016/j.solener.2004.09.003 · DOI · Paper page
Berger A., Segalman R. A., Newman J., Energy. Environ. Sci. 7, 1468–1476 (2014).
10.1021/jp102533v · DOI · Paper page
10.1073/pnas.1114672109 · DOI
10.1038/nchem.1621 · DOI · Paper page
10.1021/ja4071893 · DOI
N. Wiberg E. Wiberg A. F. Holleman in Inorganic Chemistry (Academic Press San Diego CA 2001) vol. 1.
10.1016/0022-0728(87)80225-5 · doi:10.1016/0022-0728(87)80225-5
10.1016/j.ijhydene.2009.01.047 · DOI · Paper page
10.1126/science.1215868 · DOI · Paper page
10.1039/c1sc00117e · DOI · Paper page
10.1021/ic00028a007 · doi:10.1021/ic00028a007
LaConti A. B., Liu H., Mittelsteadt C., McDonald R. C., ECS Trans. 1, 199–219 (2006). · DOI
10.1007/s10800-012-0490-5 · DOI · Paper page
10.1016/j.apcatb.2011.10.020 · DOI · Paper page
10.1126/science.1246913 · DOI · Paper page
10.1126/science.1227775 · DOI · Paper page
10.1002/anie.201300136 · DOI · Paper page
10.1016/j.electacta.2011.10.044 · DOI · Paper page
10.1016/j.ijhydene.2009.09.015 · DOI · Paper page
10.1016/j.ijhydene.2011.04.031 · doi:10.1016/j.ijhydene.2011.04.031
10.1016/j.ijhydene.2011.06.019 · DOI
C. H. Hamann Electrochemistry (Wiley-VCH ed. 2 Xxxxxx XX 2007).
10.1016/0022-1902(76)80361-2 · doi:10.1016/0022-1902(76)80361-2
10.1016/j.electacta.2007.11.027 · doi:10.1016/j.electacta.2007.11.027
10.1016/j.ijhydene.2012.12.010 · DOI · Paper page
10.1016/j.ijhydene.2010.07.013 · DOI
10.1016/j.ijhydene.2010.05.041 · DOI · Paper page
10.1016/j.ijhydene.2010.01.153 · DOI
10.1016/j.ijhydene.2009.06.061 · DOI
10.1016/j.electacta.2008.04.009 · DOI

Earth-abundant catalysts for electrochemical and photoelectrochemical water splitting
Roger, I., Shipman, M. A., & Symes, M. D. (2017) · Nature Reviews Chemistry · doi:10.1038/s41570-016-0003 · Cited by 3,503
Self-citation
Electronic and Morphological Dual Modulation of Cobalt Carbonate Hydroxides by Mn Doping toward Highly Efficient and Stable Bifunctional Electrocatalysts for Overall Water Splitting
Tang, T., Jiang, W.-J., Niu, S., Liu, N., Luo, H., Chen, Y.-Y., Jin, S.-F., Gao, F., Wan, L.-J., & Hu, J.-S. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b03507 · Cited by 880
Bifunctional Electrocatalysts for Overall and Hybrid Water Splitting
Quan, L., Jiang, H., Mei, G., Sun, Y., & You, B. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00332 · Cited by 874
Highly efficient hydrogen evolution from seawater by a low-cost and stable CoMoP@ C electrocatalyst superior to Pt/C
Ma, Y.-Y., Wu, C.-X., Feng, X.-J., Tan, H.-Q., Yan, L.-K., Liu, Y., Kang, Z.-H., Wang, E.-B., & Li, Y.-G. (2017) · Energy & Environmental Science · doi:10.1039/c6ee03768b · Cited by 781
Photoelectrochemical water splitting in separate oxygen and hydrogen cells
Landman, A., Dotan, H., Shter, G. E., Wullenkord, M., Houaijia, A., Maljusch, A., Grader, G. S., & Rothschild, A. (2017) · Nature Materials · doi:10.1038/nmat4876 · Cited by 572

See all 770

Authors: Rausch, B., Symes, M. D., Chisholm, G., & Cronin, L.
Venue: Science
Publisher: American Association for the Advancement of Science (AAAS)
Published: 2014-09-12
Volume: 345
Issue: 6202
Pages: 1326-1330
ISSN: 0036-8075 (ISSN-L)
1095-9203
DOI: 10.1126/science.1257443
OpenAlex: W2037991128
Cited by: 770
References: 1
FWCI: 12.88
Type: journal article
Language: en
Open access: closed

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This page: CoChat. (2026). Citation check: Decoupled catalytic hydrogen evolution from a molecular metal oxide redox mediator in water splitting. https://app.cochat.ai/papers/10.1126/science.1257443
The paper: Rausch, B., Symes, M. D., Chisholm, G., & Cronin, L. (2014). Decoupled catalytic hydrogen evolution from a molecular metal oxide redox mediator in water splitting. Science. https://doi.org/10.1126/science.1257443

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Decoupled catalytic hydrogen evolution from a molecular metal oxide redox mediator in water splitting

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