The DOI matches its Crossref record; 26 of the 26 references it cites were found in a registry or an index.
High Flux Thin Film Nanocomposite Membranes Based on Metal–Organic Frameworks for Organic Solvent Nanofiltration
Abstract
Thin-film nanocomposite membranes containing a range of 50-150 nm metal-organic framework (MOF) nanoparticles [ZIF-8, MIL-53(Al), NH2-MIL-53(Al) and MIL-101(Cr)] in a polyamide (PA) thin film layer were synthesized via in situ interfacial polymerization on top of cross-linked polyimide porous supports. MOF nanoparticles were homogeneously dispersed in the organic phase containing trimesoyl chloride prior to the interfacial reaction, and their subsequent presence in the PA layer formed was inferred by a combination of contact angle measurements, FT-IR spectroscopy, SEM, EDX, XPS, and TEM. Membrane performance in organic solvent nanofiltration was evaluated on the basis of methanol (MeOH) and tetrahydrofuran (THF) permeances and rejection of styrene oligomers (PS). The effect of different post-treatments and MOF loadings on the membrane performance was also investigated. MeOH and THF permeance increased when MOFs were embedded into the PA layer, whereas the rejection remained higher than 90% (molecular weight cutoff of less than 232 and 295 g·mol(-1) for MeOH and THF, respectively) in all membranes. Moreover, permeance enhancement increased with increasing pore size and porosity of the MOF used as filler. The incorporation of nanosized MIL-101(Cr), with the largest pore size of 3.4 nm, led to an exceptional increase in permeance, from 1.5 to 3.9 and from 1.7 to 11.1 L·m(-2)·h(-1)·bar(-1) for MeOH/PS and THF/PS, respectively.
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Cites
Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
Park, K. S., Ni, Z., Côté, A. P., Choi, J. Y., Huang, R., Uribe-Romo, F. J., Chae, H. K., O’Keeffe, M., & Yaghi, O. M. (2006) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0602439103 · Cited by 7,563
A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area
Férey, G., Mellot-Draznieks, C., Serre, C., Millange, F., Dutour, J., Surblé, S., & Margiolaki, I. (2005) · Science · doi:10.1126/science.1116275 · Cited by 5,430
Composite reverse osmosis and nanofiltration membranes
Petersen, R. J. (1993) · Journal of Membrane Science · doi:10.1016/0376-7388(93)80014-o · Cited by 1,743
Interfacial polymerization of thin film nanocomposites: A new concept for reverse osmosis membranes
Jeong, B.-H., Hoek, E. M. V., Yan, Y., Subramani, A., Huang, X., Hurwitz, G., Ghosh, A. K., & Jawor, A. (2007) · Journal of Membrane Science · doi:10.1016/j.memsci.2007.02.025 · Cited by 1,307
Bux, H., Liang, F., Li, Y., Cravillon, J., Wiebcke, M., & Caro, J. (2009) · Journal of the American Chemical Society · doi:10.1021/ja907359t · Cited by 1,250
Solvent resistant nanofiltration: separating on a molecular level
Vandezande, P., Gevers, L. E. M., & Vankelecom, I. F. J. (2008) · Chem. Soc. Rev. · doi:10.1039/b610848m · Cited by 1,155
An Amine-Functionalized MIL-53 Metal−Organic Framework with Large Separation Power for CO 2 and CH 4
Couck, S., Denayer, J. F. M., Baron, G. V., Rémy, T., Gascon, J., & Kapteijn, F. (2009) · Journal of the American Chemical Society · doi:10.1021/ja900555r · Cited by 988
Highly Permeable Zeolite Imidazolate Framework-8 Membranes for CO2/CH4 Separation
Venna, S. R., & Carreon, M. A. (2010) · Journal of the American Chemical Society · doi:10.1021/ja909263x · Cited by 956
Thin films of metal–organic frameworks
Zacher, D., Shekhah, O., Wöll, C., & Fischer, R. A. (2009) · Chemical Society Reviews · doi:10.1039/b805038b · Cited by 893
Amino-based metal-organic frameworks as stable, highly active basic catalysts
GASCON, J., AKTAY, U., HERNANDEZALONSO, M., VANKLINK, G., & KAPTEIJN, F. (2009) · Journal of Catalysis · doi:10.1016/j.jcat.2008.11.010 · Cited by 667
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Yin, J., & Deng, B. (2015) · Journal of Membrane Science · doi:10.1016/j.memsci.2014.11.019 · Cited by 1,089
Metal–organic frameworks for membrane-based separations
Denny, M. S., Moreton, J. C., Benz, L., & Cohen, S. M. (2016) · Nature Reviews Materials · doi:10.1038/natrevmats.2016.78 · Cited by 820
Lau, W. J., Gray, S., Matsuura, T., Emadzadeh, D., Paul Chen, J., & Ismail, A. F. (2015) · Water Research · doi:10.1016/j.watres.2015.04.037 · Cited by 773
Metal–organic frameworks based membranes for liquid separation
Li, X., Liu, Y., Wang, J., Gascon, J., Li, J., & Van der Bruggen, B. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00575j · Cited by 747
Zhu, L., Zong, L., Wu, X., Li, M., Wang, H., You, J., & Li, C. (2018) · ACS Nano · doi:10.1021/acsnano.8b00566 · Cited by 455
Metadata
- Authors
- Sorribas, S., Gorgojo, P., Téllez, C., Coronas, J., & Livingston, A. G.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-09-30
- Volume
- 135
- Issue
- 40
- Pages
- 15201-15208
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2013288358
- Cited by
- 773
- References
- 26
- FWCI
- 32.88
- Type
- journal article
- Language
- en
- Open access
- closed
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- Sorribas, S., Gorgojo, P., Téllez, C., Coronas, J., & Livingston, A. G. (2013). High Flux Thin Film Nanocomposite Membranes Based on Metal–Organic Frameworks for Organic Solvent Nanofiltration. Journal of the American Chemical Society. https://doi.org/10.1021/ja407665w
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