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Cited by 167

The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.

Robust Cuprous Phenanthroline Sensitizer for Solar Hydrogen Photocatalysis

Open access
Khnayzer, Rony S., McCusker, Catherine E., Olaiya, Babatunde S., Castellano, Felix N.·2013·Journal of the American Chemical Society

Abstract

The Cu(I) metal-to-ligand charge-transfer complex, [Cu(dsbtmp)2](+) (dsbtmp = 2,9-di(sec-butyl)-3,4,7,8-tetramethyl-1,10-phenanthroline), exhibits outstanding stability as a visible-light-absorbing photosensitizer in hydrogen-evolving homogeneous photocatalysis. In concert with the Co(dmgH)2(py)Cl water reduction catalyst and N,N-dimethyl-p-toluidine sacrificial donor in 1:1 H2O:CH3CN, this Cu(I) sensitizer remains active even after 5 days of visible-light-pumped (λex = 452 ± 10 nm) hydrogen evolution catalysis. Deuteration studies illustrate that the hydrogen produced from this composition does indeed originate from aqueous protons.

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Metadata

Authors
Khnayzer, R. S., McCusker, C. E., Olaiya, B. S., & Castellano, F. N.
Venue
Journal of the American Chemical Society
Published
2013-09-17
Volume
135
Issue
38
Pages
14068-14070
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2318077607
Cited by
167
References
1
FWCI
5.77
Type
journal article
Language
en
Open access
hybrid

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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