The DOI matches its Crossref record; 33 of the 33 references it cites were found in a registry or an index.
Solid Solution Alloy Nanoparticles of Immiscible Pd and Ru Elements Neighboring on Rh: Changeover of the Thermodynamic Behavior for Hydrogen Storage and Enhanced CO-Oxidizing Ability
Abstract
Pd(x)Ru(1-x) solid solution alloy nanoparticles were successfully synthesized over the whole composition range through a chemical reduction method, although Ru and Pd are immiscible at the atomic level in the bulk state. From the XRD measurement, it was found that the dominant structure of Pd(x)Ru(1-x) changes from fcc to hcp with increasing Ru content. The structures of Pd(x)Ru(1-x) nanoparticles in the Pd composition range of 30-70% consisted of both solid solution fcc and hcp structures, and both phases coexist in a single particle. In addition, the reaction of hydrogen with the Pd(x)Ru(1-x) nanoparticles changed from exothermic to endothermic as the Ru content increased. Furthermore, the prepared Pd(x)Ru(1-x) nanoparticles demonstrated enhanced CO-oxidizing catalytic activity; Pd0.5Ru0.5 nanoparticles exhibit the highest catalytic activity. This activity is much higher than that of the practically used CO-oxidizing catalyst Ru and that of the neighboring Rh, between Ru and Pd.
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Cited by
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Metadata
- Authors
- Kusada, K., Kobayashi, H., Ikeda, R., Kubota, Y., Takata, M., Toh, S., Yamamoto, T., Matsumura, S., Sumi, N., Sato, K., Nagaoka, K., & Kitagawa, H.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-01-23
- Volume
- 136
- Issue
- 5
- Pages
- 1864-1871
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1976184370
- Cited by
- 275
- References
- 33
- FWCI
- 9.08
- Type
- journal article
- Language
- en
- Open access
- closed
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