The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Armored MOFs: Enforcing Soft Microporous MOF Nanocrystals with Hard Mesoporous Silica
Abstract
Metal-organic frameworks (MOFs) are a class of fascinating supramolecular soft matters but with relatively weak mechanical strength. To enforce MOF materials for practical applications, one possible way seems to be transforming them into harder composites with a stronger secondary phase. Apparently, such a reinforcing phase must possess larger porosity for ionic or molecular species to travel into or out of MOFs without altering their pristine physicochemical properties. Herein we report a general synthetic approach to coat microporous MOFs and their derivatives with an enforcing shell of mesoporous silica (mSiO2). Four well-known MOFs (ZIF-8, ZIF-7, UiO-66, and HKUST-1), representing two important families of MOFs, have served as a core phase in nanocomposite products. We show that significant enhancement in mechanical properties (hardness and toughness) can indeed be achieved with this "armoring approach". Excellent accessibility of the mSiO2-wrapped MOFs and their metal-containing nanocomposites has also been demonstrated with catalytic reduction of 4-nitrophenol.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Ordered porous materials for emerging applications
Davis, M. E. (2002) · Nature · doi:10.1038/nature00785 · Cited by 5,308
Metal-organic frameworks with high capacity and selectivity for harmful gases
Britt, D., Tranchemontagne, D., & Yaghi, O. M. (2008) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0804900105 · Cited by 958
Tan, J. C., & Cheetham, A. K. (2011) · Chemical Society Reviews · doi:10.1039/c0cs00163e · Cited by 762
Tan, J. C., Bennett, T. D., & Cheetham, A. K. (2010) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1003205107 · Cited by 552
Cited by
Metal–Organic Framework-Based Hierarchically Porous Materials: Synthesis and Applications
Cai, G., Yan, P., Zhang, L., Zhou, H.-C., & Jiang, H.-L. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00243 · Cited by 1,631
The surface chemistry of metal–organic frameworks
McGuire, C. V., & Forgan, R. S. (2015) · Chemical Communications · doi:10.1039/c4cc04458d · Cited by 396
Recent advances in Prussian blue and Prussian blue analogues: synthesis and thermal treatments
Zakaria, M. B., & Chikyow, T. (2017) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.09.014 · Cited by 389
Metadata
- Authors
- Li, Z., & Zeng, H. C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-04-02
- Volume
- 136
- Issue
- 15
- Pages
- 5631-5639
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2316204623
- Cited by
- 184
- References
- 5
- FWCI
- 6.91
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
