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The DOI matches its Crossref record; 317 of the 317 references it cites were found in a registry or an index.

Metal–Organic Framework-Based Hierarchically Porous Materials: Synthesis and Applications

Cai, Guorui, Yan, Peng, Zhang, Liangliang, Zhou, Hong-Cai, Jiang, Hai-Long·2021·Chemical Reviews

Abstract

Metal-organic frameworks (MOFs) have been widely recognized as one of the most fascinating classes of materials from science and engineering perspectives, benefiting from their high porosity and well-defined and tailored structures and components at the atomic level. Although their intrinsic micropores endow size-selective capability and high surface area, etc., the narrow pores limit their applications toward diffusion-control and large-size species involved processes. In recent years, the construction of hierarchically porous MOFs (HP-MOFs), MOF-based hierarchically porous composites, and MOF-based hierarchically porous derivatives has captured widespread interest to extend the applications of conventional MOF-based materials. In this Review, the recent advances in the design, synthesis, and functional applications of MOF-based hierarchically porous materials are summarized. Their structural characters toward various applications, including catalysis, gas storage and separation, air filtration, sewage treatment, sensing and energy storage, have been demonstrated with typical reports. The comparison of HP-MOFs with traditional porous materials (e.g., zeolite, porous silica, carbons, metal oxides, and polymers), subsisting challenges, as well as future directions in this research field, are also indicated.

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Metadata

Authors
Cai, G., Yan, P., Zhang, L., Zhou, H.-C., & Jiang, H.-L.
Venue
Chemical Reviews
Published
2021-07-19
Volume
121
Issue
20
Pages
12278-12326
ISSN
  • 0009-2665 (ISSN-L)
  • 1520-6890
OpenAlex
W3185024652
Cited by
1,631
References
317
FWCI
8.43
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Metal–Organic Framework-Based Hierarchically Porous Materials: Synthesis and Applications. https://app.cochat.ai/papers/10.1021/acs.chemrev.1c00243
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Cai, G., Yan, P., Zhang, L., Zhou, H.-C., & Jiang, H.-L. (2021). Metal–Organic Framework-Based Hierarchically Porous Materials: Synthesis and Applications. Chemical Reviews. https://doi.org/10.1021/acs.chemrev.1c00243

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