The DOI matches its Crossref record; 15 of the 15 references it cites were found in a registry or an index.
Deep-Ultraviolet Nonlinear Optical Crystals: Ba3P3O10X (X = Cl, Br)
Abstract
Deep-ultraviolet nonlinear optical (deep-UV NLO) crystals are of worldwide interest for the generation of coherent light with wavelength below 200 nm by the direct second-harmonic generation (SHG) output from solid-state lasers. The unprecedented deep-UV NLO phosphates representing their own structure types, Ba3P3O10Cl (BPOC), Ba3P3O10Br (BPOB), have been discovered, which display moderate powder SHG intensities in type I phase matchable behaviors with a short UV cutoff edge of 180 nm (measured by a single crystal, one of the shortest values among phosphates to date). Insightfully, the geometry and polarization of the C1-P3O10(5-) building unit are affected by the crystal packing. DFT calculations and cutoff energy dependent SHG coefficient analyses reveal that the SHG origin is from the cooperation of asymmetric C1-P3O10(5-) anion, Ba(2+) cation, and Cl(-)/Br(-) anion.
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Cited by
Two Non-π-Conjugated Deep-UV Nonlinear Optical Sulfates
Li, Y., Liang, F., Zhao, S., Li, L., Wu, Z., Ding, Q., Liu, S., Lin, Z., Hong, M., & Luo, J. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b00138 · Cited by 268
Metadata
- Authors
- Yu, P., Wu, L.-M., Zhou, L.-J., & Chen, L.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-12-27
- Volume
- 136
- Issue
- 1
- Pages
- 480-487
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2327933395
- Cited by
- 459
- References
- 15
- FWCI
- 5.65
- Type
- journal article
- Language
- en
- Open access
- closed
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