The DOI matches its Crossref record; 13 of the 13 references it cites were found in a registry or an index.
Two Non-π-Conjugated Deep-UV Nonlinear Optical Sulfates
Abstract
The non-π-conjugated sulfate system has long been overlooked as potential deep-UV nonlinear optical (NLO) materials. Here we report two asymmetric anhydrous sulfates, namely, NH 4 NaLi 2 (SO 4 ) 2 ( Ι ) and (NH 4 ) 2 Na 3 Li 9 (SO 4 ) 7 ( Π ), which consist of non-π-conjugated [SO 4 ] 2– anions. Their single crystals can be readily grown by a facile evaporation method from water solution. Both sulfates are transparent down to the deep-UV region. Interestingly, there is a large NLO gap between I and Π, with phase-matching NLO responses of 1.1 and 0.5 times that of the benchmark KH 2 PO 4, respectively. The first-principles studies reveal that the non-π-conjugated [SO 4 ] 2– anions are the dominate NLO-active groups, and the large NLO gap between I and Π can be ascribed to the nonbonding O 2 p orbitals of different orientations in the crystallographically independent S1O 4 groups. This work provides an innovative non-π-conjugated source that is distinct from the traditional π-conjugated ones for deep-UV NLO materials.
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Clark, S. J., Segall, M. D., Pickard, C. J., Hasnip, P. J., Probert, M. I. J., Refson, K., & Payne, M. C. (2005) · Zeitschrift für Kristallographie - Crystalline Materials · doi:10.1524/zkri.220.5.567.65075 · Cited by 14,633
Payne, M. C., Teter, M. P., Allan, D. C., Arias, T. A., & Joannopoulos, J. D. (1992) · Reviews of Modern Physics · doi:10.1103/revmodphys.64.1045 · Cited by 9,728
Giant anisotropic nonlinear optical response in transition metal monopnictide Weyl semimetals
Wu, L., Patankar, S., Morimoto, T., Nair, N. L., Thewalt, E., Little, A., Analytis, J. G., Moore, J. E., & Orenstein, J. (2017) · Nature Physics · doi:10.1038/nphys3969 · Cited by 468
Beryllium-free Li4Sr(BO3)2 for deep-ultraviolet nonlinear optical applications
Zhao, S., Gong, P., Bai, L., Xu, X., Zhang, S., Sun, Z., Lin, Z., Hong, M., Chen, C., & Luo, J. (2014) · Nature Communications · doi:10.1038/ncomms5019 · Cited by 462
Self-citationDeep-Ultraviolet Nonlinear Optical Crystals: Ba3P3O10X (X = Cl, Br)
Yu, P., Wu, L.-M., Zhou, L.-J., & Chen, L. (2014) · Journal of the American Chemical Society · doi:10.1021/ja411272y · Cited by 459
Li, L., Wang, Y., Lei, B.-H., Han, S., Yang, Z., Poeppelmeier, K. R., & Pan, S. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b06053 · Cited by 384
Self-citationHuang, H., Yao, J., Lin, Z., Wang, X., He, R., Yao, W., Zhai, N., & Chen, C. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201103960 · Cited by 369
Self-citationRbMgCO3F: A New Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material
Tran, T. T., He, J., Rondinelli, J. M., & Halasyamani, P. S. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b06519 · Cited by 341
Bera, T. K., Jang, J. I., Song, J.-H., Malliakas, C. D., Freeman, A. J., Ketterson, J. B., & Kanatzidis, M. G. (2010) · Journal of the American Chemical Society · doi:10.1021/ja9094846 · Cited by 241
Zhao, S., Yang, X., Yang, Y., Kuang, X., Lu, F., Shan, P., Sun, Z., Lin, Z., Hong, M., & Luo, J. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.7b12518 · Cited by 239
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Metadata
- Authors
- Li, Y., Liang, F., Zhao, S., Li, L., Wu, Z., Ding, Q., Liu, S., Lin, Z., Hong, M., & Luo, J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-02-21
- Volume
- 141
- Issue
- 9
- Pages
- 3833-3837
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2915457575
- Cited by
- 268
- References
- 13
- FWCI
- 9.93
- Type
- journal article
- Language
- en
- Open access
- closed
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- Li, Y., Liang, F., Zhao, S., Li, L., Wu, Z., Ding, Q., Liu, S., Lin, Z., Hong, M., & Luo, J. (2019). Two Non-π-Conjugated Deep-UV Nonlinear Optical Sulfates. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.9b00138
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