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Amorphous FeOOH Oxygen Evolution Reaction Catalyst for Photoelectrochemical Water Splitting

Chemelewski, William D., Lee, Heung-Chan, Lin, Jung-Fu, Bard, Allen J., Mullins, C. Buddie·2014·Journal of the American Chemical Society
DOI 10.1021/ja411835a
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Abstract

Reaching the goal of economical photoelectrochemical (PEC) water splitting will likely require the combination of efficient solar absorbers with high activity electrocatalysts for the hydrogen and oxygen evolution reactions (HER and OER). Toward this goal, we synthesized an amorphous FeOOH (a-FeOOH) phase that has not previously been studied as an OER catalyst. The a-FeOOH films show activity comparable to that of another OER cocatalyst, Co-borate (Co-Bi), in 1 M Na2CO3, reaching 10 mA/cm(2) at an overpotential of ∼550 mV for 10 nm thick films. Additionally, the a-FeOOH thin films absorb less than 3% of the solar photons (AM1.5G) with energy greater than 1.9 eV, are homogeneous over large areas, and act as a protective layer separating the solution from the solar absorber. The utility of a-FeOOH in a realistic system is tested by depositing on amorphous Si triple junction solar cells with a photovoltaic efficiency of 6.8%. The resulting a-FeOOH/a-Si devices achieve a total water splitting efficiency of 4.3% at 0 V vs RHE in a three-electrode configuration and show no decrease in efficiency over the course of 4 h.

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Cites

Research works printed but not linked: 45

  1. Denholm P., 2007, Energy Policy, 35, 2852, 10.1016/j.enpol.2006.10.014 · DOI
  2. Walter M. G., 2010, Chem. Rev., 110, 6446, 10.1021/cr1002326 · DOI · Paper page
  3. Osterloh F. E., 2007, Chem. Mater., 20, 35, 10.1021/cm7024203 · DOI · Paper page
  4. Osterloh F. E., 2013, Chem. Soc. Rev., 42, 2294, 10.1039/C2CS35266D · DOI · Paper page
  5. Kudo A., 2008, Chem. Soc. Rev., 38, 253, 10.1039/B800489G · DOI · Paper page
  6. Mueller-Langer F., 2007, Int. J. Hydrog. Energy, 32, 3797, 10.1016/j.ijhydene.2007.05.027 · DOI · Paper page
  7. Spath, P. L.; Mann, M. K.Life Cycle Assessment of Hydrogen Production via Natural Gas Steam Reforming;National Renewable Energy Laboratory:Golden CO, 2000. · DOI · Paper page
  8. van de Krol R., 2008, J. Mater. Chem., 18, 2311, 10.1039/b718969a · DOI · Paper page
  9. Seabold J. A., 2012, J. Am. Chem. Soc., 134, 2186, 10.1021/ja209001d · DOI · Paper page
  10. Barroso M., 2011, J. Am. Chem. Soc., 133, 14868, 10.1021/ja205325v · DOI · Paper page
  11. Tilley S. D., 2010, Angew. Chem., Int. Ed., 49, 6405, 10.1002/anie.201003110 · DOI · Paper page
  12. Kay A., 2006, J. Am. Chem. Soc., 128, 15714, 10.1021/ja064380l · DOI · Paper page
  13. Koper M. T. M., 2011, J. Electroanal. Chem., 660, 254, 10.1016/j.jelechem.2010.10.004 · DOI · Paper page
  14. Bediako D. K., 2013, J. Am. Chem. Soc., 135, 3662, 10.1021/ja3126432 · DOI · Paper page
  15. Klahr B., 2012, J. Am. Chem. Soc., 134, 16693, 10.1021/ja306427f · DOI · Paper page
  16. Barroso M., 2012, Proc. Natl. Acad. Sci., 109, 15640, 10.1073/pnas.1118326109 · DOI · Paper page
  17. Hu J.-M., 2004, Int. J. Hydrogen Energy, 29, 791, 10.1016/j.ijhydene.2003.09.007 · doi:10.1016/j.ijhydene.2003.09.007
  18. Trasatti S., 1980, J. Electroanal. Chem., 111, 125, 10.1016/S0022-0728(80)80084-2 · DOI · Paper page
  19. Bard A. J., 1995, Acc. Chem. Res., 28, 141, 10.1021/ar00051a007 · DOI · Paper page
  20. Shockley W., 1961, J. Appl. Phys., 32, 510, 10.1063/1.1736034 · DOI · Paper page
  21. Weber M. F., 1984, J. Electrochem. Soc., 131, 1258, 10.1149/1.2115797 · DOI · Paper page
  22. Bolton J. R., 1985, Nature, 316, 495, 10.1038/316495a0 · DOI · Paper page
  23. Lyons M., 2008, Int. J. Electrochem. Sci., 3, 1463, 10.1016/S1452-3981(23)15533-7 · DOI
  24. Du P., 2012, Energy Environ. Sci., 5, 6012, 10.1039/c2ee03250c · DOI · Paper page
  25. Zhong D. K., 2010, J. Am. Chem. Soc., 132, 4202, 10.1021/ja908730h · DOI · Paper page
  26. Sivula K., 2011, ChemSusChem, 4, 432, 10.1002/cssc.201000416 · DOI · Paper page
  27. Rudnick, R. L.; Gao, S.InTreatise on Geochemistry;Holland, H. D.; Turekian, K. K., Eds.Elsevier:Dordrecht, The Netherlands , 2003; Vol.3, pp1–64.
  28. Lyons M. E. G., 2009, Phys. Chem. Chem. Phys., 11, 2203, 10.1039/b815338h · DOI
  29. Lyons M. E. G., 2011, Phys. Chem. Chem. Phys., 13, 21530, 10.1039/c1cp22470k · DOI
  30. Kumar M., 2011, Int. J. Hydrogen Energy, 36, 12698, 10.1016/j.ijhydene.2011.07.029 · DOI
  31. Smith R. D. L., 2013, Science, 340, 60, 10.1126/science.1233638 · DOI · Paper page
  32. Spray R. L., 2009, Chem. Mater., 21, 3701, 10.1021/cm803099k · DOI
  33. Deng X., 2000, Sol. Energy Mater. Sol. Cells, 62, 89, 10.1016/S0927-0248(99)00139-7 · doi:10.1016/s0927-0248(99)00139-7
  34. Peulon S., 2004, Electrochim. Acta, 49, 2891, 10.1016/j.electacta.2004.01.048 · doi:10.1016/j.electacta.2004.01.048
  35. Peulon S., 2003, Electrochem. Commun., 5, 208, 10.1016/S1388-2481(03)00019-5 · DOI
  36. Esswein A. J., 2011, Energy Environ. Sci., 4, 499, 10.1039/C0EE00518E · DOI · Paper page
  37. Wiesner A. D., 2006, J. Colloid Interface Sci., 301, 329, 10.1016/j.jcis.2006.05.011 · doi:10.1016/j.jcis.2006.05.011
  38. He P., 1986, Anal. Chem., 58, 517, 10.1021/ac00294a004 · DOI
  39. Malac M., 1999, Microsc. Microanal., 5, 29, 10.1017/S1431927699000021 · doi:10.1017/s1431927699000021
  40. Welsh I. D., 1989, Phys. Rev. B, 40, 6386, 10.1103/PhysRevB.40.6386 · DOI
  41. McIntyre N. S., 1977, Anal. Chem., 49, 1521, 10.1021/ac50019a016 · DOI · Paper page
  42. Alben R., 1975, Phys. Rev. B, 11, 2271, 10.1103/PhysRevB.11.2271 · DOI · Paper page
  43. Reece S. Y., 2011, Science, 334, 645, 10.1126/science.1209816 · DOI · Paper page
  44. Minguzzi A., 2012, Chem. Sci., 3, 217, 10.1039/C1SC00516B · DOI · Paper page
  45. Surendranath Y., 2010, J. Am. Chem. Soc., 132, 16501, 10.1021/ja106102b · DOI · Paper page

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Metadata

Authors
Chemelewski, W. D., Lee, H.-C., Lin, J.-F., Bard, A. J., & Mullins, C. B.
Venue
Journal of the American Chemical Society
Publisher
American Chemical Society (ACS)
Published
2014-02-05
Volume
136
Issue
7
Pages
2843-2850
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
DOI
10.1021/ja411835a
OpenAlex
W2107790223
Cited by
603
References
4
FWCI
20.19
Type
journal article
Language
en
Open access
closed

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