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Self-Supported PdxBi Catalysts for the Electrooxidation of Glycerol in Alkaline Media

Zalineeva, Anna, Serov, Alexey, Padilla, Monica, Martinez, Ulises, Artyushkova, Kateryna, Baranton, Stève, Coutanceau, Christophe, Atanassov, Plamen B.·2014·Journal of the American Chemical Society

Abstract

Highly active self-supported PdxBi catalysts are synthesized by the sacrificial support method. Self-supported PdxBi catalysts have a porous nanostructured morphology with high surface areas (in the range from 75 to 100 m(2) g(-1)), making PdxBi a state-of-the-art catalyst. Pd4Bi displays the highest activity toward glycerol oxidation. In situ Fourier transform infrared spectroscopy highlights the unique catalytic behavior of self-supported PdxBi materials due to their particular structure and morphology. The confinement of reactants and intermediates in pores acting as nanoreactors is responsible for the high selectivity as a function of the electrode potential: aldehyde and ketone at low potentials, hydroxypyruvate at moderate potentials, and CO2 at high potentials. Moreover, the selectivity depends on the electrode history: it is different for the positive potential scan direction than for the reverse direction, where the catalyst becomes selective toward the production of carboxylates.

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Metadata

Authors
Zalineeva, A., Serov, A., Padilla, M., Martinez, U., Artyushkova, K., Baranton, S., Coutanceau, C., & Atanassov, P. B.
Venue
Journal of the American Chemical Society
Published
2014-02-27
Volume
136
Issue
10
Pages
3937-3945
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2328839106
Cited by
291
References
3
FWCI
10.04
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Self-Supported PdxBi Catalysts for the Electrooxidation of Glycerol in Alkaline Media. https://app.cochat.ai/papers/10.1021/ja412429f
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Zalineeva, A., Serov, A., Padilla, M., Martinez, U., Artyushkova, K., Baranton, S., Coutanceau, C., & Atanassov, P. B. (2014). Self-Supported PdxBi Catalysts for the Electrooxidation of Glycerol in Alkaline Media. Journal of the American Chemical Society. https://doi.org/10.1021/ja412429f

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