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Uniform, High Aspect Ratio Fiber-like Micelles and Block Co-micelles with a Crystalline π-Conjugated Polythiophene Core by Self-Seeding
Abstract
Monodisperse fiber-like micelles with a crystalline π-conjugated polythiophene core with lengths up to ca. 700 nm were successfully prepared from the diblock copolymer poly(3-hexylthiophene)-block-polystyrene using a one-dimensional self-seeding technique. Addition of a polythiophene block copolymer with a different corona-forming block to the resulting nanofibers led to the formation of segmented B-A-B triblock co-micelles by crystallization-driven seeded growth. The key to these advances appears to be the formation of a relatively defect-free crystalline micelle core under the self-seeding conditions.
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Petzetakis, N., Dove, A. P., & O'Reilly, R. K. (2011) · Chem. Sci. · doi:10.1039/c0sc00596g · Cited by 338
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Pearce, A. K., Wilks, T. R., Arno, M. C., & O’Reilly, R. K. (2020) · Nature Reviews Chemistry · doi:10.1038/s41570-020-00232-7 · Cited by 389
Tritschler, U., Pearce, S., Gwyther, J., Whittell, G. R., & Manners, I. (2017) · Macromolecules · doi:10.1021/acs.macromol.6b02767 · Cited by 375
Self-citationPolyferrocenylsilanes: synthesis, properties, and applications
Hailes, R. L. N., Oliver, A. M., Gwyther, J., Whittell, G. R., & Manners, I. (2016) · Chemical Society Reviews · doi:10.1039/c6cs00155f · Cited by 317
Self-citationSelf-Assembly of Copolymer Micelles: Higher-Level Assembly for Constructing Hierarchical Structure
Lu, Y., Lin, J., Wang, L., Zhang, L., & Cai, C. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00774 · Cited by 281
Metadata
- Authors
- Qian, J., Li, X., Lunn, D. J., Gwyther, J., Hudson, Z. M., Kynaston, E., Rupar, P. A., Winnik, M. A., & Manners, I.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-03-06
- Volume
- 136
- Issue
- 11
- Pages
- 4121-4124
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2011476984
- Cited by
- 198
- References
- 1
- FWCI
- 10.42
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Qian, J., Li, X., Lunn, D. J., Gwyther, J., Hudson, Z. M., Kynaston, E., Rupar, P. A., Winnik, M. A., & Manners, I. (2014). Uniform, High Aspect Ratio Fiber-like Micelles and Block Co-micelles with a Crystalline π-Conjugated Polythiophene Core by Self-Seeding. Journal of the American Chemical Society. https://doi.org/10.1021/ja500661k
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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