The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Oxygen Vacancies Confined in Ultrathin Indium Oxide Porous Sheets for Promoted Visible-Light Water Splitting
Abstract
Finding an ideal model for disclosing the role of oxygen vacancies in photocatalysis remains a huge challenge. Herein, O-vacancies confined in atomically thin sheets is proposed as an excellent platform to study the O-vacancy-photocatalysis relationship. As an example, O-vacancy-rich/-poor 5-atom-thick In2O3 porous sheets are first synthesized via a mesoscopic-assembly fast-heating strategy, taking advantage of an artificial hexagonal mesostructured In-oleate complex. Theoretical/experimental results reveal that the O-vacancies endow 5-atom-thick In2O3 sheets with a new donor level and increased states of density, hence narrowing the band gap from the UV to visible regime and improving the carrier separation efficiency. As expected, the O-vacancy-rich ultrathin In2O3 porous sheets-based photoelectrode exhibits a visible-light photocurrent of 1.73 mA/cm(2), over 2.5 and 15 times larger than that of the O-vacancy-poor ultrathin In2O3 porous sheets- and bulk In2O3-based photoelectrodes.
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Citations
Cites
Electrochemical Photolysis of Water at a Semiconductor Electrode
FUJISHIMA, A., & HONDA, K. (1972) · Nature · doi:10.1038/238037a0 · Cited by 34,169
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Iridium Single Atoms Coupling with Oxygen Vacancies Boosts Oxygen Evolution Reaction in Acid Media
Yin, J., Jin, J., Lu, M., Huang, B., Zhang, H., Peng, Y., Xi, P., & Yan, C.-H. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c05050 · Cited by 545
Wu, R., Zhang, J., Shi, Y., Liu, D., & Zhang, B. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b01330 · Cited by 517
Oxygen vacancies in metal oxides: recent progress towards advanced catalyst design
Zhuang, G., Chen, Y., Zhuang, Z., Yu, Y., & Yu, J. (2020) · Science China Materials · doi:10.1007/s40843-020-1305-6 · Cited by 499
Surface Modification of 2D Photocatalysts for Solar Energy Conversion
Feng, C., Wu, Z., Huang, K., Ye, J., & Zhang, H. (2022) · Advanced Materials · doi:10.1002/adma.202200180 · Cited by 456
Metadata
- Authors
- Lei, F., Sun, Y., Liu, K., Gao, S., Liang, L., Pan, B., & Xie, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-05-02
- Volume
- 136
- Issue
- 19
- Pages
- 6826-6829
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1972336064
- Cited by
- 1,390
- References
- 1
- FWCI
- 24.89
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lei, F., Sun, Y., Liu, K., Gao, S., Liang, L., Pan, B., & Xie, Y. (2014). Oxygen Vacancies Confined in Ultrathin Indium Oxide Porous Sheets for Promoted Visible-Light Water Splitting. Journal of the American Chemical Society. https://doi.org/10.1021/ja501866r
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