The DOI matches its Crossref record; 33 of the 33 references it cites were found in a registry or an index.
Metal–Organic Frameworks with Precisely Designed Interior for Carbon Dioxide Capture in the Presence of Water
Open accessAbstract
The selective capture of carbon dioxide in the presence of water is an outstanding challenge. Here, we show that the interior of IRMOF-74-III can be covalently functionalized with primary amine (IRMOF-74-III-CH2NH2) and used for the selective capture of CO2 in 65% relative humidity. This study encompasses the synthesis, structural characterization, gas adsorption, and CO2 capture properties of variously functionalized IRMOF-74-III compounds (IRMOF-74-III-CH3, -NH2, -CH2NHBoc, -CH2NMeBoc, -CH2NH2, and -CH2NHMe). Cross-polarization magic angle spinning (13)C NMR spectra showed that CO2 binds chemically to IRMOF-74-III-CH2NH2 and -CH2NHMe to make carbamic species. Carbon dioxide isotherms and breakthrough experiments show that IRMOF-74-III-CH2NH2 is especially efficient at taking up CO2 (3.2 mmol of CO2 per gram at 800 Torr) and, more significantly, removing CO2 from wet nitrogen gas streams with breakthrough time of 610 ± 10 s g(-1) and full preservation of the IRMOF structure.
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Cites
The Chemistry and Applications of Metal-Organic Frameworks
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Self-citationCarbon Dioxide Capture in Metal–Organic Frameworks
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Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation
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Self-citationPost-Combustion CO 2 Capture Using Solid Sorbents: A Review
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Cited by
Carbon capture and conversion using metal–organic frameworks and MOF-based materials
Ding, M., Flaig, R. W., Jiang, H.-L., & Yaghi, O. M. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00829a · Cited by 2,616
Self-citationThe chemistry of metal–organic frameworks for CO2 capture, regeneration and conversion
Trickett, C. A., Helal, A., Al-Maythalony, B. A., Yamani, Z. H., Cordova, K. E., & Yaghi, O. M. (2017) · Nature Reviews Materials · doi:10.1038/natrevmats.2017.45 · Cited by 1,524
Self-citationApplications of water stable metal–organic frameworks
Wang, C., Liu, X., Keser Demir, N., Chen, J. P., & Li, K. (2016) · Chemical Society Reviews · doi:10.1039/c6cs00362a · Cited by 1,249
CO2 Capture and Separations Using MOFs: Computational and Experimental Studies
Yu, J., Xie, L.-H., Li, J.-R., Ma, Y., Seminario, J. M., & Balbuena, P. B. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00626 · Cited by 1,047
Structures of Metal–Organic Frameworks with Rod Secondary Building Units
Schoedel, A., Li, M., Li, D., O’Keeffe, M., & Yaghi, O. M. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00346 · Cited by 909
Self-citation
Metadata
- Authors
- Fracaroli, A. M., Furukawa, H., Suzuki, M., Dodd, M., Okajima, S., Gándara, F., Reimer, J. A., & Yaghi, O. M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-06-16
- Volume
- 136
- Issue
- 25
- Pages
- 8863-8866
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2314697832
- Cited by
- 425
- References
- 33
- FWCI
- 23.70
- Type
- journal article
- Language
- en
- Open access
- green
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- Fracaroli, A. M., Furukawa, H., Suzuki, M., Dodd, M., Okajima, S., Gándara, F., Reimer, J. A., & Yaghi, O. M. (2014). Metal–Organic Frameworks with Precisely Designed Interior for Carbon Dioxide Capture in the Presence of Water. Journal of the American Chemical Society. https://doi.org/10.1021/ja503296c
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