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Efficient Planar Perovskite Solar Cells Based on 1.8 eV Band Gap CH3NH3PbI2Br Nanosheets via Thermal Decomposition

Zhao, Yixin, Zhu, Kai·2014·Journal of the American Chemical Society

Abstract

Hybrid organometallic halide perovskite CH3NH3PbI2Br (or MAPbI2Br) nanosheets with a 1.8 eV band gap were prepared via a thermal decomposition process from a precursor containing PbI2, MABr, and MACl. The planar solar cell based on the compact layer of MAPbI2Br nanosheets exhibited 10% efficiency and a single-wavelength conversion efficiency of up to 86%. The crystal phase, optical absorption, film morphology, and thermogravimetric analysis studies indicate that the thermal decomposition process strongly depends on the composition of precursors. We find that MACl functions as a glue or soft template to control the initial formation of a solid solution with the main MAPbI2Br precursor components (i.e., PbI2 and MABr). The subsequent thermal decomposition process controls the morphology/surface coverage of perovskite films on the planar substrate and strongly affects the device characteristics.

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Metadata

Authors
Zhao, Y., & Zhu, K.
Venue
Journal of the American Chemical Society
Published
2014-08-21
Volume
136
Issue
35
Pages
12241-12244
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2329062199
Cited by
242
References
1
FWCI
19.81
Type
journal article
Language
en
Open access
closed

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