The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Monitoring the Solid-State Electrochemistry of Cu(2,7-AQDC) (AQDC = Anthraquinone Dicarboxylate) in a Lithium Battery: Coexistence of Metal and Ligand Redox Activities in a Metal–Organic Framework
Abstract
By adopting a facile synthetic strategy, we obtained a microporous redox-active metal-organic framework (MOF), namely, Cu(2,7-AQDC) (2,7-H2AQDC = 2,7-anthraquinonedicarboxylic acid) (1), and utilized it as a cathode active material in lithium batteries. With a voltage window of 4.0-1.7 V, both metal clusters and anthraquinone groups in the ligands exhibited reversible redox activity. The valence change of copper cations was clearly evidenced by in situ XANES analysis. By controlling the voltage window of operation, extremely high recyclability of batteries was achieved, suggesting the framework was robust. This MOF is the first example of a porous material showing independent redox activity on both metal cluster nodes and ligand sites.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Armand, M., & Tarascon, J.-M. (2008) · Nature · doi:10.1038/451652a · Cited by 19,612
Cited by
Metal–organic frameworks for energy storage: Batteries and supercapacitors
Wang, L., Han, Y., Feng, X., Zhou, J., Qi, P., & Wang, B. (2016) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2015.09.002 · Cited by 1,298
Metal-Organic Frameworks for Energy Applications
Wang, H., Zhu, Q.-L., Zou, R., & Xu, Q. (2017) · Chem · doi:10.1016/j.chempr.2016.12.002 · Cited by 1,200
Pristine Metal–Organic Frameworks and their Composites for Energy Storage and Conversion
Liang, Z., Qu, C., Guo, W., Zou, R., & Xu, Q. (2018) · Advanced Materials · doi:10.1002/adma.201702891 · Cited by 787
Liu, J., & Wöll, C. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00315c · Cited by 698
Nam, K. W., Park, S. S., dos Reis, R., Dravid, V. P., Kim, H., Mirkin, C. A., & Stoddart, J. F. (2019) · Nature Communications · doi:10.1038/s41467-019-12857-4 · Cited by 688
Metadata
- Authors
- Zhang, Z., Yoshikawa, H., & Awaga, K.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-11-10
- Volume
- 136
- Issue
- 46
- Pages
- 16112-16115
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2318050461
- Cited by
- 315
- References
- 1
- FWCI
- 11.01
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Monitoring the Solid-State Electrochemistry of Cu(2,7-AQDC) (AQDC = Anthraquinone Dicarboxylate) in a Lithium Battery: Coexistence of Metal and Ligand Redox Activities in a Metal–Organic Framework. https://app.cochat.ai/papers/10.1021/ja508197w
- The paper
- Zhang, Z., Yoshikawa, H., & Awaga, K. (2014). Monitoring the Solid-State Electrochemistry of Cu(2,7-AQDC) (AQDC = Anthraquinone Dicarboxylate) in a Lithium Battery: Coexistence of Metal and Ligand Redox Activities in a Metal–Organic Framework. Journal of the American Chemical Society. https://doi.org/10.1021/ja508197w
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
