The DOI matches its Crossref record; 33 of the 33 references it cites were found in a registry or an index.
Mechanistic Insight into Size-Dependent Activity and Durability in Pt/CNT Catalyzed Hydrolytic Dehydrogenation of Ammonia Borane
Open accessAbstract
We report a size-dependent activity in Pt/CNT catalyzed hydrolytic dehydrogenation of ammonia borane. Kinetic study and model calculations revealed that Pt(111) facet is the dominating catalytically active surface. There is an optimized Pt particle size of ca. 1.8 nm. Meanwhile, the catalyst durability was found to be highly sensitive to the Pt particle size. The smaller Pt particles appear to have lower durability, which could be related to more significant adsorption of B-containing species on Pt surfaces as well as easier changes in Pt particle size and shape. The insights reported here may pave the way for the rational design of highly active and durable Pt catalysts for hydrogen generation.
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Cites
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Cited by
Dehydrogenation of Ammonia Borane by Metal Nanoparticle Catalysts
Zhan, W.-W., Zhu, Q.-L., & Xu, Q. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02209 · Cited by 481
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Khalily, M. A., Eren, H., Akbayrak, S., Susapto, H. H., Biyikli, N., Özkar, S., & Guler, M. O. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201605577 · Cited by 181
Progress in fabrication of one-dimensional catalytic materials by electrospinning technology
Zhu, S., & Nie, L. (2021) · Journal of Industrial and Engineering Chemistry · doi:10.1016/j.jiec.2020.09.016 · Cited by 91
Xin, Y., Dong, L., Guo, Y., Liu, X., Hu, Y., & Wang, Y. (2019) · Journal of Catalysis · doi:10.1016/j.jcat.2019.05.007 · Cited by 86
Metadata
- Authors
- Chen, W., Ji, J., Feng, X., Duan, X., Qian, G., Li, P., Zhou, X., Chen, D., & Yuan, W.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-11-21
- Volume
- 136
- Issue
- 48
- Pages
- 16736-16739
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2326452575
- Cited by
- 334
- References
- 33
- FWCI
- 12.06
- Type
- journal article
- Language
- en
- Open access
- green
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- Chen, W., Ji, J., Feng, X., Duan, X., Qian, G., Li, P., Zhou, X., Chen, D., & Yuan, W. (2014). Mechanistic Insight into Size-Dependent Activity and Durability in Pt/CNT Catalyzed Hydrolytic Dehydrogenation of Ammonia Borane. Journal of the American Chemical Society. https://doi.org/10.1021/ja509778y
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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