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Transformation of the Excited State and Photovoltaic Efficiency of CH3NH3PbI3 Perovskite upon Controlled Exposure to Humidified Air
Open accessAbstract
Humidity has been an important factor, in both negative and positive ways, in the development of perovskite solar cells and will prove critical in the push to commercialize this exciting new photovoltaic technology. The interaction between CH(3)NH(3)PbI(3) and H(2)O vapor is investigated by characterizing the ground-state and excited-state optical absorption properties and probing morphology and crystal structure. These undertakings reveal that H(2)O exposure does not simply cause CH(3)NH(3)PbI(3) to revert to PbI(2). It is shown that, in the dark, H(2)O is able to complex with the perovskite, forming a hydrate product similar to (CH(3)NH(3))(4)PbI(6)·2H(2)O. This causes a decrease in absorption across the visible region of the spectrum and a distinct change in the crystal structure of the material. Femtosecond transient absorption spectroscopic measurements show the effect that humidity has on the ultrafast excited state dynamics of CH(3)NH(3)PbI(3). More importantly, the deleterious effects of humidity on complete solar cells, specifically on photovoltaic efficiency and stability, are explored in the light of these spectroscopic understandings.
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Stranks, S. D., Eperon, G. E., Grancini, G., Menelaou, C., Alcocer, M. J. P., Leijtens, T., Herz, L. M., Petrozza, A., & Snaith, H. J. (2013) · Science · doi:10.1126/science.1243982 · Cited by 10,413
Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts
Luo, J., Im, J.-H., Mayer, M. T., Schreier, M., Nazeeruddin, M. K., Park, N.-G., Tilley, S. D., Fan, H. J., & Grätzel, M. (2014) · Science · doi:10.1126/science.1258307 · Cited by 2,509
Cited by
A Review of Perovskites Solar Cell Stability
Wang, R., Mujahid, M., Duan, Y., Wang, Z., Xue, J., & Yang, Y. (2019) · Advanced Functional Materials · doi:10.1002/adfm.201808843 · Cited by 1,310
Stability of Metal Halide Perovskite Solar Cells
Leijtens, T., Eperon, G. E., Noel, N. K., Habisreutinger, S. N., Petrozza, A., & Snaith, H. J. (2015) · Advanced Energy Materials · doi:10.1002/aenm.201500963 · Cited by 1,308
Li, X., Hoffman, J. M., & Kanatzidis, M. G. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c01006 · Cited by 1,085
Thermochromic halide perovskite solar cells
Lin, J., Lai, M., Dou, L., Kley, C. S., Chen, H., Peng, F., Sun, J., Lu, D., Hawks, S. A., Xie, C., et al. (2018) · Nature Materials · doi:10.1038/s41563-017-0006-0 · Cited by 853
The Importance of Moisture in Hybrid Lead Halide Perovskite Thin Film Fabrication
Eperon, G. E., Habisreutinger, S. N., Leijtens, T., Bruijnaers, B. J., van Franeker, J. J., deQuilettes, D. W., Pathak, S., Sutton, R. J., Grancini, G., Ginger, D. S., et al. (2015) · ACS Nano · doi:10.1021/acsnano.5b03626 · Cited by 574
Metadata
- Authors
- Christians, J. A., Miranda Herrera, P. A., & Kamat, P. V.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-01-27
- Volume
- 137
- Issue
- 4
- Pages
- 1530-1538
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1991981401
- Cited by
- 1,367
- References
- 2
- FWCI
- 77.46
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Christians, J. A., Miranda Herrera, P. A., & Kamat, P. V. (2015). Transformation of the Excited State and Photovoltaic Efficiency of CH3NH3PbI3 Perovskite upon Controlled Exposure to Humidified Air. Journal of the American Chemical Society. https://doi.org/10.1021/ja511132a
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