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Thermal Conversion of Core–Shell Metal–Organic Frameworks: A New Method for Selectively Functionalized Nanoporous Hybrid Carbon

Tang, Jing, Salunkhe, Rahul R., Liu, Jian, Torad, Nagy L., Imura, Masataka, Furukawa, Shuhei, Yamauchi, Yusuke·2015·Journal of the American Chemical Society

Abstract

Core-shell structured ZIF-8@ZIF-67 crystals are well-designed and prepared through a seed-mediated growth method. After thermal treatment of ZIF-8@ZIF-67 crystals, we obtain selectively functionalized nanoporous hybrid carbon materials consisting of nitrogen-doped carbon (NC) as the cores and highly graphitic carbon (GC) as the shells. This is the first example of the integration of NC and GC in one particle at the nanometer level. Electrochemical data strongly demonstrate that this nanoporous hybrid carbon material integrates the advantageous properties of the individual NC and GC, exhibiting a distinguished specific capacitance (270 F·g(-1)) calculated from the galvanostatic charge-discharge curves at a current density of 2 A·g(-1). Our study not only bridges diverse carbon-based materials with infinite metal-organic frameworks but also opens a new avenue for artificially designed nanoarchitectures with target functionalities.

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Metadata

Authors
Tang, J., Salunkhe, R. R., Liu, J., Torad, N. L., Imura, M., Furukawa, S., & Yamauchi, Y.
Venue
Journal of the American Chemical Society
Published
2015-01-27
Volume
137
Issue
4
Pages
1572-1580
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2025925068
Cited by
1,506
References
3
FWCI
58.69
Type
journal article
Language
en
Open access
closed

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