The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Crystallization Kinetics of Organic–Inorganic Trihalide Perovskites and the Role of the Lead Anion in Crystal Growth
Open accessAbstract
Methylammonium lead halide perovskite solar cells continue to excite the research community due to their rapidly increasing performance which, in large part, is due to improvements in film morphology. The next step in this progression is control of the crystal morphology which requires a better fundamental understanding of the crystal growth. In this study we use in situ X-ray scattering data to study isothermal transformations of perovskite films derived from chloride, iodide, nitrate, and acetate lead salts. Using established models we determine the activation energy for crystallization and find that it changes as a function of the lead salt. Further analysis enabled determination of the precursor composition and showed that the primary step in perovskite formation is removal of excess organic salt from the precursor. This understanding suggests that careful choice of the lead salt will aid in controlling crystal growth, leading to superior films and better performing solar cells.
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Cites
Kim, H.-S., Lee, C.-R., Im, J.-H., Lee, K.-B., Moehl, T., Marchioro, A., Moon, S.-J., Humphry-Baker, R., Yum, J.-H., Moser, J. E., et al. (2012) · Scientific Reports · doi:10.1038/srep00591 · Cited by 8,092
Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells
Jeon, N. J., Noh, J. H., Kim, Y. C., Yang, W. S., Ryu, S., & Seok, S. I. (2014) · Nature Materials · doi:10.1038/nmat4014 · Cited by 6,723
Cited by
Metal-halide perovskites for photovoltaic and light-emitting devices
Stranks, S. D., & Snaith, H. J. (2015) · Nature Nanotechnology · doi:10.1038/nnano.2015.90 · Cited by 3,392
Self-citationUnderstanding the physical properties of hybrid perovskites for photovoltaic applications
Huang, J., Yuan, Y., Shao, Y., & Yan, Y. (2017) · Nature Reviews Materials · doi:10.1038/natrevmats.2017.42 · Cited by 1,252
Fu, Y., Zhu, H., Chen, J., Hautzinger, M. P., Zhu, X.-Y., & Jin, S. (2019) · Nature Reviews Materials · doi:10.1038/s41578-019-0080-9 · Cited by 934
Present status and future prospects of perovskite photovoltaics
Snaith, H. J. (2018) · Nature Materials · doi:10.1038/s41563-018-0071-z · Cited by 803
Self-citationCauses and Solutions of Recombination in Perovskite Solar Cells
Chen, J., & Park, N. (2019) · Advanced Materials · doi:10.1002/adma.201803019 · Cited by 733
Metadata
- Authors
- Moore, D. T., Sai, H., Tan, K. W., Smilgies, D.-M., Zhang, W., Snaith, H. J., Wiesner, U., & Estroff, L. A.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-02-09
- Volume
- 137
- Issue
- 6
- Pages
- 2350-2358
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2087052492
- Cited by
- 380
- References
- 2
- FWCI
- 24.22
- Type
- journal article
- Language
- en
- Open access
- green
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- Moore, D. T., Sai, H., Tan, K. W., Smilgies, D.-M., Zhang, W., Snaith, H. J., Wiesner, U., & Estroff, L. A. (2015). Crystallization Kinetics of Organic–Inorganic Trihalide Perovskites and the Role of the Lead Anion in Crystal Growth. Journal of the American Chemical Society. https://doi.org/10.1021/ja512117e
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