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Sequential Linker Installation: Precise Placement of Functional Groups in Multivariate Metal–Organic Frameworks
Abstract
A unique strategy, sequential linker installation (SLI), has been developed to construct multivariate MOFs with functional groups precisely positioned. PCN-700, a Zr-MOF with eight-connected Zr6O4(OH)8(H2O)4 clusters, has been judiciously designed; the Zr6 clusters in this MOF are arranged in such a fashion that, by replacement of terminal OH(-)/H2O ligands, subsequent insertion of linear dicarboxylate linkers is achieved. We demonstrate that linkers with distinct lengths and functionalities can be sequentially installed into PCN-700. Single-crystal to single-crystal transformation is realized so that the positions of the subsequently installed linkers are pinpointed via single-crystal X-ray diffraction analyses. This methodology provides a powerful tool to construct multivariate MOFs with precisely positioned functionalities in the desired proximity, which would otherwise be difficult to achieve.
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Cited by
Zr-based metal–organic frameworks: design, synthesis, structure, and applications
Bai, Y., Dou, Y., Xie, L.-H., Rutledge, W., Li, J.-R., & Zhou, H.-C. (2016) · Chemical Society Reviews · doi:10.1039/c5cs00837a · Cited by 2,545
Self-citationFrom fundamentals to applications: a toolbox for robust and multifunctional MOF materials
Kirchon, A., Feng, L., Drake, H. F., Joseph, E. A., & Zhou, H.-C. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00688a · Cited by 1,448
Self-citationShearer, G. C., Chavan, S., Bordiga, S., Svelle, S., Olsbye, U., & Lillerud, K. P. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.6b00602 · Cited by 1,437
A versatile MOF-based trap for heavy metal ion capture and dispersion
Peng, Y., Huang, H., Zhang, Y., Kang, C., Chen, S., Song, L., Liu, D., & Zhong, C. (2018) · Nature Communications · doi:10.1038/s41467-017-02600-2 · Cited by 804
Stable Metal–Organic Frameworks with Group 4 Metals: Current Status and Trends
Yuan, S., Qin, J.-S., Lollar, C. T., & Zhou, H.-C. (2018) · ACS Central Science · doi:10.1021/acscentsci.8b00073 · Cited by 561
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Metadata
- Authors
- Yuan, S., Lu, W., Chen, Y.-P., Zhang, Q., Liu, T.-F., Feng, D., Wang, X., Qin, J., & Zhou, H.-C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-03-03
- Volume
- 137
- Issue
- 9
- Pages
- 3177-3180
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2052966503
- Cited by
- 421
- References
- 0
- FWCI
- 16.76
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yuan, S., Lu, W., Chen, Y.-P., Zhang, Q., Liu, T.-F., Feng, D., Wang, X., Qin, J., & Zhou, H.-C. (2015). Sequential Linker Installation: Precise Placement of Functional Groups in Multivariate Metal–Organic Frameworks. Journal of the American Chemical Society. https://doi.org/10.1021/ja512762r
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