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Reticular Synthesis of Covalent Organic Borosilicate Frameworks
Abstract
This paper reports the synthesis and characterization of a new crystalline 3D covalent organic framework, COF-202: [C(C6H4)4]3[B3O6 (tBuSi)2]4, formed from condensation of a divergent boronic acid, tetra(4-dihydroxyborylphenyl)methane, and tert-butylsilane triol, tBuSi(OH)3. This framework is constructed through strong covalent bonds (Si-O, B-O) that link triangular and tetrahedral building units to form a structure based on the carbon nitride topology. COF-202 demonstrates high thermal stability, low density, and high porosity with a surface area of 2690 m2 g-1. The design and synthesis of COF-202 expand the type of linkage that could be used to crystallize new materials with extended covalent organic frameworks.
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Cited by
Covalent Organic Framework Photocatalysts: Structures and Applications
Wang, H., Wang, H., Wang, Z., Tang, L., Zeng, G., Xu, P., Chen, M., Xiong, T., Zhou, C., Li, X., et al. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00278j · Cited by 1,301
Liu, R., Tan, K. T., Gong, Y., Chen, Y., Li, Z., Xie, S., He, T., Lu, Z., Yang, H., & Jiang, D. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00620c · Cited by 1,083
Han, S. S., Mendoza-Cortés, J. L., & Goddard III, W. A. (2009) · Chemical Society Reviews · doi:10.1039/b802430h · Cited by 594
Beuerle, F., & Gole, B. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201710190 · Cited by 528
Porous Organic Polymers for Post‐Combustion Carbon Capture
Zou, L., Sun, Y., Che, S., Yang, X., Wang, X., Bosch, M., Wang, Q., Li, H., Smith, M., Yuan, S., et al. (2017) · Advanced Materials · doi:10.1002/adma.201700229 · Cited by 432
Vinylene‐Linked Covalent Organic Frameworks by Base‐Catalyzed Aldol Condensation
Acharjya, A., Pachfule, P., Roeser, J., Schmitt, F., & Thomas, A. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201905886 · Cited by 341
Metadata
- Authors
- Hunt, J. R., Doonan, C. J., LeVangie, J. D., Côté, A. P., & Yaghi, O. M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-08-16
- Volume
- 130
- Issue
- 36
- Pages
- 11872-11873
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2073402336
- Cited by
- 433
- References
- 0
- FWCI
- 9.43
- Type
- journal article
- Language
- en
- Open access
- closed
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