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Self-Assembly of Organic−Inorganic Hybrid Amphiphilic Surfactants with Large Polyoxometalates as Polar Head Groups
Abstract
Mn-Anderson-C6 and Mn-Anderson-C16, A type of inorganic-organic hybrid molecules containing a large anionic polyoxometalate (POM) cluster and two C6 and C16 alkyl chains, respectively, demonstrate amphiphilic surfactant behavior in the mixed solvents of acetonitrile and water. The amphiphilic hybrid molecules can slowly assemble into membrane-like vesicles by using the POM clusters as polar head groups, as studied by laser light scattering and TEM techniques. The hollow vesicles have a typical bilayer structure with the hydrophilic Mn-Anderson cluster facing outside and long hydrophobic alkyl chains staying inside to form the solvent-phobic layer. Due to the rigidity of the POM polar heads, the two alkyl tails have to bend significantly for the vesicle formation, which makes the vesicle formation more difficult compared to some conventional surfactants. This is the first example of using hydrophilic POM macroions as polar head groups for a surfactant system.
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Cited by
Hybrid Organic−Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications
Dolbecq, A., Dumas, E., Mayer, C. R., & Mialane, P. (2010) · Chemical Reviews · doi:10.1021/cr1000578 · Cited by 1,755
Recent advances on polyoxometalate-based molecular and composite materials
Song, Y.-F., & Tsunashima, R. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35143a · Cited by 909
Self-citationBeyond Charge Balance: Counter‐Cations in Polyoxometalate Chemistry
Misra, A., Kozma, K., Streb, C., & Nyman, M. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.201905600 · Cited by 482
CO2-responsive polymeric materials: synthesis, self-assembly, and functional applications
Darabi, A., Jessop, P. G., & Cunningham, M. F. (2016) · Chemical Society Reviews · doi:10.1039/c5cs00873e · Cited by 391
Li, M., Guan, Y., Zhao, A., Ren, J., & Qu, X. (2017) · Theranostics · doi:10.7150/thno.18459 · Cited by 90
Metadata
- Authors
- Zhang, J., Song, Y.-F., Cronin, L., & Liu, T.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-10-08
- Volume
- 130
- Issue
- 44
- Pages
- 14408-14409
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2028471058
- Cited by
- 305
- References
- 0
- FWCI
- 12.80
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhang, J., Song, Y.-F., Cronin, L., & Liu, T. (2008). Self-Assembly of Organic−Inorganic Hybrid Amphiphilic Surfactants with Large Polyoxometalates as Polar Head Groups. Journal of the American Chemical Society. https://doi.org/10.1021/ja805644a
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