The DOI matches its Crossref record; 15 of the 15 references it cites were found in a registry or an index.
Activating Pd by Morphology Tailoring for Oxygen Reduction
Abstract
Pd has been the focus of recent research for Pt-alternative catalysts for the oxygen reduction reaction (ORR). It has been found that upon appropriate modification of its electronic structure, the catalytic activity of Pd can become comparable to that of Pt. However, the structure-activity relationships of Pd catalysts have hitherto not been well studied or understood. In the present work, we report a new finding that there is a strong dependence of the activity of Pd toward the ORR on its morphology. By simply adjusting the precursor concentration in the electrochemical deposition of Pd, we are able to tailor the morphology of the deposited Pd from nanoparticles to nanorods. Surprisingly, the surface-specific activity of Pd nanorods (Pd-NRs) toward the ORR was found to be not only 10-fold higher than that of Pd nanoparticles (Pd-NPs), the conventional shape of electrocatalysts, but also comparable to that of Pt at operating potentials of fuel cell cathodes. The morphology-activity relationships of Pd-NRs were further studied through a combination of electrochemical experiments and density functional theory (DFT) calculations. As revealed by its characteristic profile for CO stripping, the morphology of Pd-NRs features the exposure of Pd(110) facets, which exhibit superior ORR activity. The underlying mechanism, indicated by DFT calculations, could be ascribed to the exceptionally weak interaction between an O adatom and a Pd(110) facet. This finding furthers our understanding of Pd catalysis and casts a new light on the relevant catalyst design criteria.
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Citations
Cites
Improved Oxygen Reduction Activity on Pt 3 Ni(111) via Increased Surface Site Availability
Stamenkovic, V. R., Fowler, B., Mun, B. S., Wang, G., Ross, P. N., Lucas, C. A., & Marković, N. M. (2007) · Science · doi:10.1126/science.1135941 · Cited by 4,421
Trends in electrocatalysis on extended and nanoscale Pt-bimetallic alloy surfaces
Stamenkovic, V. R., Mun, B. S., Arenz, M., Mayrhofer, K. J. J., Lucas, C. A., Wang, G., Ross, P. N., & Markovic, N. M. (2007) · Nature Materials · doi:10.1038/nmat1840 · Cited by 3,252
Tian, N., Zhou, Z.-Y., Sun, S.-G., Ding, Y., & Wang, Z. L. (2007) · Science · doi:10.1126/science.1140484 · Cited by 3,073
Zhang, J., Vukmirovic, M. B., Xu, Y., Mavrikakis, M., & Adzic, R. R. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200462335 · Cited by 1,106
Stamenkovic, V. R., Mun, B. S., Mayrhofer, K. J. J., Ross, P. N., & Markovic, N. M. (2006) · Journal of the American Chemical Society · doi:10.1021/ja0600476 · Cited by 974
Particle Size Effects for Oxygen Reduction on Highly Dispersed Platinum in Acid Electrolytes
Kinoshita, K. (1990) · Journal of The Electrochemical Society · doi:10.1149/1.2086566 · Cited by 854
Wang, C., Daimon, H., Onodera, T., Koda, T., & Sun, S. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200800073 · Cited by 849
Koh, S., & Strasser, P. (2007) · Journal of the American Chemical Society · doi:10.1021/ja0742784 · Cited by 783
Morphological Control of Catalytically Active Platinum Nanocrystals
Lee, H., Habas, S. E., Kweskin, S., Butcher, D., Somorjai, G. A., & Yang, P. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200603068 · Cited by 659
Adsorption and Dissociation of O 2 on Pt−Co and Pt−Fe Alloys
Xu, Y., Ruban, A. V., & Mavrikakis, M. (2004) · Journal of the American Chemical Society · doi:10.1021/ja031701+ · Cited by 636
Synthesis of Monodisperse Pt Nanocubes and Their Enhanced Catalysis for Oxygen Reduction
Wang, C., Daimon, H., Lee, Y., Kim, J., & Sun, S. (2007) · Journal of the American Chemical Society · doi:10.1021/ja070440r · Cited by 555
Electrocatalytic Activity of Ordered Intermetallic Phases for Fuel Cell Applications
Casado-Rivera, E., Volpe, D. J., Alden, L., Lind, C., Downie, C., Vázquez-Alvarez, T., Angelo, A. C. D., DiSalvo, F. J., & Abruña, H. D. (2004) · Journal of the American Chemical Society · doi:10.1021/ja038497a · Cited by 521
Origin of Enhanced Activity in Palladium Alloy Electrocatalysts for Oxygen Reduction Reaction
Shao, M., Liu, P., Zhang, J., & Adzic, R. (2007) · The Journal of Physical Chemistry B · doi:10.1021/jp0689971 · Cited by 307
Bimetallic and Ternary Alloys for Improved Oxygen Reduction Catalysis
Nilekar, A. U., Xu, Y., Zhang, J., Vukmirovic, M. B., Sasaki, K., Adzic, R. R., & Mavrikakis, M. (2007) · Topics in Catalysis · doi:10.1007/s11244-007-9001-z · Cited by 216
Yano, H., Inukai, J., Uchida, H., Watanabe, M., Babu, P. K., Kobayashi, T., Chung, J. H., Oldfield, E., & Wieckowski, A. (2006) · Physical Chemistry Chemical Physics · doi:10.1039/b610573d · Cited by 187
Cited by
Recent Advances in Electrocatalysts for Oxygen Reduction Reaction
Shao, M., Chang, Q., Dodelet, J.-P., & Chenitz, R. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00462 · Cited by 3,903
Recent advancements in Pt and Pt-free catalysts for oxygen reduction reaction
Nie, Y., Li, L., & Wei, Z. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00484a · Cited by 2,156
Oxygen Reduction in Alkaline Media: From Mechanisms to Recent Advances of Catalysts
Ge, X., Sumboja, A., Wuu, D., An, T., Li, B., Goh, F. W. T., Hor, T. S. A., Zong, Y., & Liu, Z. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00524 · Cited by 1,341
Koenigsmann, C., & Wong, S. S. (2011) · Energy Environ. Sci. · doi:10.1039/c0ee00197j · Cited by 392
Palladium alloys used as electrocatalysts for the oxygen reduction reaction
Wang, T., Chutia, A., Brett, D. J. L., Shearing, P. R., He, G., Chai, G., & Parkin, I. P. (2021) · Energy & Environmental Science · doi:10.1039/d0ee03915b · Cited by 322
Metadata
- Authors
- Xiao, L., Zhuang, L., Liu, Y., & Lu, J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-12-24
- Volume
- 131
- Issue
- 2
- Pages
- 602-608
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2028785773
- Cited by
- 467
- References
- 15
- FWCI
- 19.43
- Type
- journal article
- Language
- en
- Open access
- closed
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