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Ordered Mesoporous Alumina-Supported Metal Oxides

Morris, Stacy M., Fulvio, Pasquale F., Jaroniec, Mietek·2008·Journal of the American Chemical Society

Abstract

The one-pot synthesis of alumina-supported metal oxides via self-assembly of a metal precursor and aluminum isopropoxide in the presence of triblock copolymer (as a structure directing agent) is described in detail for nickel oxide. The resulting mesoporous mixed metal oxides possess p6 mm hexagonal symmetry, well-developed mesoporosity, relatively high BET surface area, large pore widths, and crystalline pore walls. In comparison to pure alumina, nickel aluminum oxide samples exhibited larger mesopores and improved thermal stability. Also, long-range ordering of the aforementioned samples was observed for nickel molar percentages as high as 20%. The generality of the recipe used for the synthesis of mesoporous nickel aluminum oxide was demonstrated by preparation of other alumina-supported metal oxides such as MgO, CaO, TiO 2, and Cr 2O 3. This method represents an important step toward the facile and reproducible synthesis of ordered mesoporous alumina-supported materials for various applications where large and accessible pores with high loading of catalytically active metal oxides are needed.

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Metadata

Authors
Morris, S. M., Fulvio, P. F., & Jaroniec, M.
Venue
Journal of the American Chemical Society
Published
2008-10-16
Volume
130
Issue
45
Pages
15210-15216
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2010578002
Cited by
384
References
2
FWCI
7.92
Type
journal article
Language
en
Open access
closed

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