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Highly Stable Performance of Supercapacitors from Phosphorus-Enriched Carbons
Open accessAbstract
Phosphorus-rich microporous carbons (P-carbons) prepared by a simple H(3)PO(4) activation of three different carbon precursors exhibit enhanced supercapacitive performance in 1 M H(2)SO(4) when highly stable performance can be achieved at potentials larger than the theoretical decomposition potential of water. This ability of P-carbons greatly enhances the energy density of supercapacitors that are capable of delivering 16 Wh/kg compared to 5 Wh/kg for the commercial carbon. An intercept-free multiple linear regression model confirms the strongest influence of phosphorus on capacitance together with micropores 0.65-0.83 nm in width that are the most effective in forming the electric double layer.
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Cited by
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Liu, W.-J., Jiang, H., & Yu, H.-Q. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00195 · Cited by 1,754
Electrolyte selection for supercapacitive devices: a critical review
Pal, B., Yang, S., Ramesh, S., Thangadurai, V., & Jose, R. (2019) · Nanoscale Advances · doi:10.1039/c9na00374f · Cited by 1,317
Wang, Q., Yan, J., & Fan, Z. (2016) · Energy & Environmental Science · doi:10.1039/c5ee03109e · Cited by 1,225
Nitrogen-containing microporous carbon nanospheres with improved capacitive properties
Su, F., Poh, C. K., Chen, J. S., Xu, G., Wang, D., Li, Q., Lin, J., & Lou, X. W. (2011) · Energy Environ. Sci. · doi:10.1039/c0ee00277a · Cited by 916
Metadata
- Authors
- Hulicova-Jurcakova, D., Puziy, A. M., Poddubnaya, O. I., Suárez-García, F., Tascón, J. M. D., & Lu, G. Q.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-03-24
- Volume
- 131
- Issue
- 14
- Pages
- 5026-5027
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2023492950
- Cited by
- 604
- References
- 0
- FWCI
- 9.36
- Type
- journal article
- Language
- en
- Open access
- green
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- Hulicova-Jurcakova, D., Puziy, A. M., Poddubnaya, O. I., Suárez-García, F., Tascón, J. M. D., & Lu, G. Q. (2009). Highly Stable Performance of Supercapacitors from Phosphorus-Enriched Carbons. Journal of the American Chemical Society. https://doi.org/10.1021/ja809265m
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