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A Crystalline Imine-Linked 3-D Porous Covalent Organic Framework
Abstract
A new crystalline porous three-dimensional covalent organic framework, termed COF-300, has been synthesized and structurally characterized. Tetrahedral tetra-(4-anilyl)-methane and linear terephthaldehyde building blocks were condensed to form imine linkages in a material whose X-ray crystal structure shows five independent diamond frameworks. Despite the interpenetration, the structure has pores of 7.2 A diameter. Thus, COF-300 shows thermal stability up to 490 degrees C and permanent porosity with a surface area of 1360 m(2) g(-1).
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Cited by
Single-crystal x-ray diffraction structures of covalent organic frameworks
Ma, T., Kapustin, E. A., Yin, S. X., Liang, L., Zhou, Z., Niu, J., Li, L.-H., Wang, Y., Su, J., Li, J., et al. (2018) · Science · doi:10.1126/science.aat7679 · Cited by 1,381
Self-citationCovalent Organic Framework Photocatalysts: Structures and Applications
Wang, H., Wang, H., Wang, Z., Tang, L., Zeng, G., Xu, P., Chen, M., Xiong, T., Zhou, C., Li, X., et al. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00278j · Cited by 1,301
Liu, R., Tan, K. T., Gong, Y., Chen, Y., Li, Z., Xie, S., He, T., Lu, Z., Yang, H., & Jiang, D. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00620c · Cited by 1,083
Fan, H., Gu, J., Meng, H., Knebel, A., & Caro, J. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201712816 · Cited by 804
Wang, H., Zeng, Z., Xu, P., Li, L., Zeng, G., Xiao, R., Tang, Z., Huang, D., Tang, L., Lai, C., et al. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00376a · Cited by 804
Metadata
- Authors
- Uribe-Romo, F. J., Hunt, J. R., Furukawa, H., Klöck, C., O’Keeffe, M., & Yaghi, O. M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-03-12
- Volume
- 131
- Issue
- 13
- Pages
- 4570-4571
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2052886839
- Cited by
- 1,715
- References
- 0
- FWCI
- 21.53
- Type
- journal article
- Language
- en
- Open access
- closed
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- Uribe-Romo, F. J., Hunt, J. R., Furukawa, H., Klöck, C., O’Keeffe, M., & Yaghi, O. M. (2009). A Crystalline Imine-Linked 3-D Porous Covalent Organic Framework. Journal of the American Chemical Society. https://doi.org/10.1021/ja8096256
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