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A Crystalline Imine-Linked 3-D Porous Covalent Organic Framework
Abstract
A new crystalline porous three-dimensional covalent organic framework, termed COF-300, has been synthesized and structurally characterized. Tetrahedral tetra-(4-anilyl)-methane and linear terephthaldehyde building blocks were condensed to form imine linkages in a material whose X-ray crystal structure shows five independent diamond frameworks. Despite the interpenetration, the structure has pores of 7.2 A diameter. Thus, COF-300 shows thermal stability up to 490 degrees C and permanent porosity with a surface area of 1360 m(2) g(-1).
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Metadata
- Authors
- Uribe-Romo, F. J., Hunt, J. R., Furukawa, H., Klöck, C., O’Keeffe, M., & Yaghi, O. M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-03-12
- Volume
- 131
- Issue
- 13
- Pages
- 4570-4571
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2052886839
- Cited by
- 1,715
- References
- 0
- FWCI
- 21.53
- Type
- journal article
- Language
- en
- Open access
- closed
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