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Post-Synthesis Alkoxide Formation Within Metal−Organic Framework Materials: A Strategy for Incorporating Highly Coordinatively Unsaturated Metal Ions
Abstract
A new noncatenated metal-organic framework containing pendant alcohol functionalities was synthesized. The alcohols were then post-synthetically converted to either lithium or magnesium alkoxides, with the incorporated metals anchored far from nodes or carboxylate functionalities. The metal alkoxide sites can be obtained stoichiometrically while maintaining the permanent porosity and large surface area of the parent hydroxylated material. The incorporated metal ions are found to induce an unusual pattern of binding energetics for H(2): isosteric heats of adsorption increase, rather than decrease, with increasing H(2) loading. Additionally, at 1 atm and 77 K, uptake (at least with low Li(+) loading) is increased by two hydrogen molecules per Li(+).
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Cited by
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Bae, Y., & Snurr, R. Q. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201101891 · Cited by 1,208
Yu, X., Tang, Z., Sun, D., Ouyang, L., & Zhu, M. (2017) · Progress in Materials Science · doi:10.1016/j.pmatsci.2017.03.001 · Cited by 716
High-throughput computational screening of metal–organic frameworks
Colón, Y. J., & Snurr, R. Q. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00070f · Cited by 470
Petrovic, B., Gorbounov, M., & Masoudi Soltani, S. (2021) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2020.110751 · Cited by 381
Zheng, S.-T., Bu, J. T., Li, Y., Wu, T., Zuo, F., Feng, P., & Bu, X. (2010) · Journal of the American Chemical Society · doi:10.1021/ja106903p · Cited by 373
Metadata
- Authors
- Mulfort, K. L., Farha, O. K., Stern, C. L., Sarjeant, A. A., & Hupp, J. T.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-02-26
- Volume
- 131
- Issue
- 11
- Pages
- 3866-3868
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1993037438
- Cited by
- 316
- References
- 0
- FWCI
- 22.77
- Type
- journal article
- Language
- en
- Open access
- closed
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- Mulfort, K. L., Farha, O. K., Stern, C. L., Sarjeant, A. A., & Hupp, J. T. (2009). Post-Synthesis Alkoxide Formation Within Metal−Organic Framework Materials: A Strategy for Incorporating Highly Coordinatively Unsaturated Metal Ions. Journal of the American Chemical Society. https://doi.org/10.1021/ja809954r
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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