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A Porous Coordination Copolymer with over 5000 m2/g BET Surface Area
Abstract
New levels of surface area are achieved in a coordination polymer (UMCM-2, University of Michigan Crystalline Material) derived from zinc-mediated coordination copolymerization of a dicarboxylic and tricarboxylic acid. In addition to a large micropore contribution to the surface area, mesopores are also present. In contrast to the recently reported coordination copolymer UMCM-1, which has a mesoporous channel, UMCM-2 is built from three types of cages. In spite of exceptional porosity, both of these coordination polymers are thermally robust. Hydrogen uptake performance of UMCM-2 approaches 7 wt% at 77 K.
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Cited by
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Furukawa, H., Cordova, K. E., O’Keeffe, M., & Yaghi, O. M. (2013) · Science · doi:10.1126/science.1230444 · Cited by 16,945
Postsynthetic Methods for the Functionalization of Metal–Organic Frameworks
Cohen, S. M. (2012) · Chemical Reviews · doi:10.1021/cr200179u · Cited by 2,336
Farha, O. K., Özgür Yazaydın, A., Eryazici, I., Malliakas, C. D., Hauser, B. G., Kanatzidis, M. G., Nguyen, S. T., Snurr, R. Q., & Hupp, J. T. (2010) · Nature Chemistry · doi:10.1038/nchem.834 · Cited by 1,741
Metal–Organic Framework-Based Hierarchically Porous Materials: Synthesis and Applications
Cai, G., Yan, P., Zhang, L., Zhou, H.-C., & Jiang, H.-L. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00243 · Cited by 1,631
Adsorptive separation on metal–organic frameworks in the liquid phase
Van de Voorde, B., Bueken, B., Denayer, J., & De Vos, D. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00006d · Cited by 874
Metadata
- Authors
- Koh, K., Wong-Foy, A. G., & Matzger, A. J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-03-06
- Volume
- 131
- Issue
- 12
- Pages
- 4184-4185
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2136471159
- Cited by
- 487
- References
- 0
- FWCI
- 36.36
- Type
- journal article
- Language
- en
- Open access
- closed
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- Koh, K., Wong-Foy, A. G., & Matzger, A. J. (2009). A Porous Coordination Copolymer with over 5000 m2/g BET Surface Area. Journal of the American Chemical Society. https://doi.org/10.1021/ja809985t
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