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Synthesis, Structure, Assembly, and Modulation of the CO2 Adsorption Properties of a Zinc-Adeninate Macrocycle
Abstract
The preparation and self-assembly of zinc adeninate macrocycles [Zn(6)(adeninate)(6)(pyridine)(6)(dimethylcarbamate)(6)] is described. The macrocycles self-assemble through adenine-adenine hydrogen bonding interactions into a 3-D porous crystalline material that maintains its structural integrity after removal of guest molecules and coordinated pyridine molecules. By adjusting the activation temperature prior to gas adsorption measurements, the size of the pore aperture can be modulated to afford unique gas sorption properties including selective gas adsorption and CO(2) sequestration.
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Cited by
Metal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
An, J., Geib, S. J., & Rosi, N. L. (2010) · Journal of the American Chemical Society · doi:10.1021/ja909169x · Cited by 937
Self-citationAn, J., Shade, C. M., Chengelis-Czegan, D. A., Petoud, S., & Rosi, N. L. (2011) · Journal of the American Chemical Society · doi:10.1021/ja109103t · Cited by 624
Self-citationZheng, S.-T., Bu, J. T., Li, Y., Wu, T., Zuo, F., Feng, P., & Bu, X. (2010) · Journal of the American Chemical Society · doi:10.1021/ja106903p · Cited by 373
Metadata
- Authors
- An, J., Fiorella, R. P., Geib, S. J., & Rosi, N. L.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-06-02
- Volume
- 131
- Issue
- 24
- Pages
- 8401-8403
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2046552754
- Cited by
- 160
- References
- 0
- FWCI
- 11.59
- Type
- journal article
- Language
- en
- Open access
- closed
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- An, J., Fiorella, R. P., Geib, S. J., & Rosi, N. L. (2009). Synthesis, Structure, Assembly, and Modulation of the CO2 Adsorption Properties of a Zinc-Adeninate Macrocycle. Journal of the American Chemical Society. https://doi.org/10.1021/ja901869m
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