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Synthesis, Structure, Assembly, and Modulation of the CO2 Adsorption Properties of a Zinc-Adeninate Macrocycle

An, Jihyun, Fiorella, Richard P., Geib, Steven J., Rosi, Nathaniel L.·2009·Journal of the American Chemical Society

Abstract

The preparation and self-assembly of zinc adeninate macrocycles [Zn(6)(adeninate)(6)(pyridine)(6)(dimethylcarbamate)(6)] is described. The macrocycles self-assemble through adenine-adenine hydrogen bonding interactions into a 3-D porous crystalline material that maintains its structural integrity after removal of guest molecules and coordinated pyridine molecules. By adjusting the activation temperature prior to gas adsorption measurements, the size of the pore aperture can be modulated to afford unique gas sorption properties including selective gas adsorption and CO(2) sequestration.

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Metadata

Authors
An, J., Fiorella, R. P., Geib, S. J., & Rosi, N. L.
Venue
Journal of the American Chemical Society
Published
2009-06-02
Volume
131
Issue
24
Pages
8401-8403
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2046552754
Cited by
160
References
0
FWCI
11.59
Type
journal article
Language
en
Open access
closed

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An, J., Fiorella, R. P., Geib, S. J., & Rosi, N. L. (2009). Synthesis, Structure, Assembly, and Modulation of the CO2 Adsorption Properties of a Zinc-Adeninate Macrocycle. Journal of the American Chemical Society. https://doi.org/10.1021/ja901869m

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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.