The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Enantioselective α-Trifluoromethylation of Aldehydes via Photoredox Organocatalysis
Open accessAbstract
The first enantioselective, organocatalytic alpha-trifluoromethylation and alpha-perfluoroalkylation of aldehydes have been accomplished using a readily available iridium photocatalyst and a chiral imidazolidinone catalyst. A range of alpha-trifluoromethyl and alpha-perfluoroalkyl aldehydes were obtained from commercially available perfluoroalkyl halides with high efficiency and enantioselectivity. The resulting alpha-trifluoromethyl aldehydes were subsequently shown to be versatile precursors for the construction of a variety of enantioenriched trifluoromethylated building blocks.
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Citations
Cites
Organofluorine Chemistry: Principles and Commercial Applications
(1994) · doi:10.1007/978-1-4899-1202-2 · Cited by 1,691
Cited by
Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Self-citationWang, J., Sánchez-Roselló, M., Aceña, J. L., del Pozo, C., Sorochinsky, A. E., Fustero, S., Soloshonok, V. A., & Liu, H. (2014) · Chemical Reviews · doi:10.1021/cr4002879 · Cited by 4,847
Visible light photocatalysis as a greener approach to photochemical synthesis
Yoon, T. P., Ischay, M. A., & Du, J. (2010) · Nature Chemistry · doi:10.1038/nchem.687 · Cited by 2,657
Photoredox Catalysis with Visible Light
Zeitler, K. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200904056 · Cited by 991
Nguyen, J. D., Tucker, J. W., Konieczynska, M. D., & Stephenson, C. R. J. (2011) · Journal of the American Chemical Society · doi:10.1021/ja108560e · Cited by 772
Metadata
- Authors
- Nagib, D. A., Scott, M. E., & MacMillan, D. W. C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-07-20
- Volume
- 131
- Issue
- 31
- Pages
- 10875-10877
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W142358202
- Cited by
- 988
- References
- 1
- FWCI
- 54.63
- Type
- journal article
- Language
- en
- Open access
- green
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