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Tin Nanoparticles Encapsulated in Porous Multichannel Carbon Microtubes: Preparation by Single-Nozzle Electrospinning and Application as Anode Material for High-Performance Li-Based Batteries
Abstract
Tin nanoparticles encapsulated in porous multichannel carbon microtubes (denoted as SPMCTs) were prepared by carbonization of electrospun PAN-PMMA-tin octoate nanofibers fabricated using a single-nozzle electrospinning technique. This material exhibited excellent characteristics for lithium ion battery anode applications in terms of reversible capacities, cycling performance, and rate capability. Undertaking such a production configuration allows the long-existing problem of obtaining a high packing density of tin particles while retaining sufficient spare space to buffer the volume variation during lithium alloying and dealloying processes to be properly addressed. Furthermore, the porous carbon shell preserves both the mechanical and chemical stability of the function-active Sn metal, which also serves as a highly conductive medium allowing Li(+) to access.
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Citations
Cited by
Carbon Nanofibers Prepared via Electrospinning
Inagaki, M., Yang, Y., & Kang, F. (2012) · Advanced Materials · doi:10.1002/adma.201104940 · Cited by 801
Zhang, B., Kang, F., Tarascon, J.-M., & Kim, J.-K. (2016) · Progress in Materials Science · doi:10.1016/j.pmatsci.2015.08.002 · Cited by 720
Porous electrode materials for lithium-ion batteries–how to prepare them and what makes them special
Vu, A., Qian, Y., & Stein, A. (2012) · Advanced Energy Materials · doi:10.1002/aenm.201200320 · Cited by 719
Nanoparticles meet electrospinning: recent advances and future prospects
Zhang, C.-L., & Yu, S.-H. (2014) · Chemical Society Reviews · doi:10.1039/c3cs60426h · Cited by 665
Zhou, L., Zhang, K., Hu, Z., Tao, Z., Mai, L., Kang, Y., Chou, S., & Chen, J. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201701415 · Cited by 593
Metadata
- Authors
- Yu, Y., Gu, L., Zhu, C., van Aken, P. A., & Maier, J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-10-20
- Volume
- 131
- Issue
- 44
- Pages
- 15984-15985
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2065898098
- Cited by
- 429
- References
- 0
- FWCI
- 19.54
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Tin Nanoparticles Encapsulated in Porous Multichannel Carbon Microtubes: Preparation by Single-Nozzle Electrospinning and Application as Anode Material for High-Performance Li-Based Batteries. https://app.cochat.ai/papers/10.1021/ja906261c
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- Yu, Y., Gu, L., Zhu, C., van Aken, P. A., & Maier, J. (2009). Tin Nanoparticles Encapsulated in Porous Multichannel Carbon Microtubes: Preparation by Single-Nozzle Electrospinning and Application as Anode Material for High-Performance Li-Based Batteries. Journal of the American Chemical Society. https://doi.org/10.1021/ja906261c
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