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Tin Nanoparticles Encapsulated in Porous Multichannel Carbon Microtubes: Preparation by Single-Nozzle Electrospinning and Application as Anode Material for High-Performance Li-Based Batteries
Abstract
Tin nanoparticles encapsulated in porous multichannel carbon microtubes (denoted as SPMCTs) were prepared by carbonization of electrospun PAN-PMMA-tin octoate nanofibers fabricated using a single-nozzle electrospinning technique. This material exhibited excellent characteristics for lithium ion battery anode applications in terms of reversible capacities, cycling performance, and rate capability. Undertaking such a production configuration allows the long-existing problem of obtaining a high packing density of tin particles while retaining sufficient spare space to buffer the volume variation during lithium alloying and dealloying processes to be properly addressed. Furthermore, the porous carbon shell preserves both the mechanical and chemical stability of the function-active Sn metal, which also serves as a highly conductive medium allowing Li(+) to access.
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Citations
Cited by
Carbon Nanofibers Prepared via Electrospinning
Inagaki, M., Yang, Y., & Kang, F. (2012) · Advanced Materials · doi:10.1002/adma.201104940 · Cited by 801
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Vu, A., Qian, Y., & Stein, A. (2012) · Advanced Energy Materials · doi:10.1002/aenm.201200320 · Cited by 719
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Zhou, L., Zhang, K., Hu, Z., Tao, Z., Mai, L., Kang, Y., Chou, S., & Chen, J. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201701415 · Cited by 593
Hollow Carbon-Nanotube/Carbon-Nanofiber Hybrid Anodes for Li-Ion Batteries
Chen, Y., Li, X., Park, K., Song, J., Hong, J., Zhou, L., Mai, Y.-W., Huang, H., & Goodenough, J. B. (2013) · Journal of the American Chemical Society · doi:10.1021/ja408421n · Cited by 444
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Dong, Z., Kennedy, S. J., & Wu, Y. (2011) · Journal of Power Sources · doi:10.1016/j.jpowsour.2011.01.090 · Cited by 437
Ultra‐Uniform SnOx/Carbon Nanohybrids toward Advanced Lithium‐Ion Battery Anodes
Zhou, X., Dai, Z., Liu, S., Bao, J., & Guo, Y. (2014) · Advanced Materials · doi:10.1002/adma.201400173 · Cited by 330
Li, W., Sun, X., & Yu, Y. (2017) · Small Methods · doi:10.1002/smtd.201600037 · Cited by 308
Self-citationPeng, S., Li, L., Kong Yoong Lee, J., Tian, L., Srinivasan, M., Adams, S., & Ramakrishna, S. (2016) · Nano Energy · doi:10.1016/j.nanoen.2016.02.001 · Cited by 304
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Liu, J., Tang, K., Song, K., van Aken, P. A., Yu, Y., & Maier, J. (2014) · Nanoscale · doi:10.1039/c3nr05329f · Cited by 296
Self-citationZhao, Y., Liang, J., Wang, C., Ma, J., & Wallace, G. G. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201702524 · Cited by 283
Seng, K. H., Park, M.-H., Guo, Z. P., Liu, H. K., & Cho, J. (2013) · Nano Letters · doi:10.1021/nl304716e · Cited by 279
Electrospun hollow nanofibers for advanced secondary batteries
Li, L., Peng, S., Lee, J. K. Y., Ji, D., Srinivasan, M., & Ramakrishna, S. (2017) · Nano Energy · doi:10.1016/j.nanoen.2017.06.050 · Cited by 267
Metadata
- Authors
- Yu, Y., Gu, L., Zhu, C., van Aken, P. A., & Maier, J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-10-20
- Volume
- 131
- Issue
- 44
- Pages
- 15984-15985
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2065898098
- Cited by
- 429
- References
- 0
- FWCI
- 19.54
- Type
- journal article
- Language
- en
- Open access
- closed
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