The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Functionalization in Flexible Porous Solids: Effects on the Pore Opening and the Host−Guest Interactions
Abstract
The synthesis on the gram scale and characterization of a series of flexible functionalized iron terephthalate MIL-53(Fe) type solids are reported. Chemical groups of various polarities, hydrophilicities, and acidities (-Cl, -Br, -CF(3), -CH(3), -NH(2), -OH, -CO(2)H) were introduced through the aromatic linker, to systematically modify the pore surface. X-ray powder diffraction (XRPD), molecular simulations, thermogravimetric analyses, and in situ IR and (57)Fe Mössbauer spectrometries indicate some similarities with the pristine MIL-53(Fe) solid, with the adoption of the narrow pore form for all solids in both the hydrated and dry forms. Combined XRPD and computational structure determinations allow concluding that the geometry of the pore opening is predominantly correlated with the intraframework interactions rather than the steric hindrance of the substituent. Only (MIL-53(Fe)-(CF(3))(2)) exhibits a nitrogen accessible porosity (S(BET) approximately 100 m(2) g(-1)). The adsorption of some liquids leads to pore openings showing some very specific behaviors depending on the guest-MIL-53(Fe) framework interactions, which can be related to the energy difference between the narrow and large pore forms evaluated by molecular simulation.
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Citations
Cites
An Amine-Functionalized MIL-53 Metal−Organic Framework with Large Separation Power for CO 2 and CH 4
Couck, S., Denayer, J. F. M., Baron, G. V., Rémy, T., Gascon, J., & Kapteijn, F. (2009) · Journal of the American Chemical Society · doi:10.1021/ja900555r · Cited by 988
Cited by
Metal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
Adsorptive separation on metal–organic frameworks in the liquid phase
Van de Voorde, B., Bueken, B., Denayer, J., & De Vos, D. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00006d · Cited by 874
Hedin, N., Andersson, L., Bergström, L., & Yan, J. (2013) · Applied Energy · doi:10.1016/j.apenergy.2012.11.034 · Cited by 424
Nitric Oxide Adsorption and Delivery in Flexible MIL-88(Fe) Metal–Organic Frameworks
McKinlay, A. C., Eubank, J. F., Wuttke, S., Xiao, B., Wheatley, P. S., Bazin, P., Lavalley, J.-C., Daturi, M., Vimont, A., De Weireld, G., et al. (2013) · Chemistry of Materials · doi:10.1021/cm304037x · Cited by 294
Self-citationFunctionalized MOFs for Enhanced CO2 Capture
Torrisi, A., Bell, R. G., & Mellot-Draznieks, C. (2010) · Crystal Growth & Design · doi:10.1021/cg100646e · Cited by 293
Metadata
- Authors
- Devic, T., Horcajada, P., Serre, C., Salles, F., Maurin, G., Moulin, B., Heurtaux, D., Clet, G., Vimont, A., Grenèche, J.-M., Ouay, B. L., Moreau, F., Magnier, E., Filinchuk, Y., Marrot, J., Lavalley, J.-C., Daturi, M., & Férey, G.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-12-28
- Volume
- 132
- Issue
- 3
- Pages
- 1127-1136
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1976431616
- Cited by
- 531
- References
- 1
- FWCI
- 21.17
- Type
- journal article
- Language
- en
- Open access
- closed
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- Devic, T., Horcajada, P., Serre, C., Salles, F., Maurin, G., Moulin, B., Heurtaux, D., Clet, G., Vimont, A., Grenèche, J.-M., Ouay, B. L., Moreau, F., Magnier, E., Filinchuk, Y., Marrot, J., Lavalley, J.-C., Daturi, M., & Férey, G. (2010). Functionalization in Flexible Porous Solids: Effects on the Pore Opening and the Host−Guest Interactions. Journal of the American Chemical Society. https://doi.org/10.1021/ja9092715
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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