The DOI matches its Crossref record.
Copolymerization of Ethylene and Propylene with Functionalized Vinyl Monomers by Palladium(II) Catalysts
Open accessAbstract
Ziegler-Natta and related catalysts based on early transition metal d0 complexes are extensively used for the coordination polymerization of nonpolar olefins such as ethylene and propylene. However, due to their highly oxophilic nature, these catalysts are incompatible with functionalized vinyl monomers. Late transition metal catalysts are less oxophilic, but they most often dimerize or oligomerize olefins rather than form high molar mass polymers. Thus, ethylene-acrylate or ethyleneviny acetate copolymers are still exclusively produced by radical routes, which often require high pressure.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Copolymerization of Polar Monomers with Olefins Using Transition-Metal Complexes
Boffa, L. S., & Novak, B. M. (2000) · Chemical Reviews · doi:10.1021/cr990251u · Cited by 962
Coordination Polymerization of Polar Vinyl Monomers by Single-Site Metal Catalysts
Chen, E. Y.-X. (2009) · Chemical Reviews · doi:10.1021/cr9000258 · Cited by 573
Synthesis of functional ‘polyolefins’: state of the art and remaining challenges
Franssen, N. M. G., Reek, J. N. H., & de Bruin, B. (2013) · Chemical Society Reviews · doi:10.1039/c3cs60032g · Cited by 485
Zhang, D., Nadres, E. T., Brookhart, M., & Daugulis, O. (2013) · Organometallics · doi:10.1021/om400704h · Cited by 261
Self-citationCatalytic Hydroxylation of Polyethylenes
Bunescu, A., Lee, S., Li, Q., & Hartwig, J. F. (2017) · ACS Central Science · doi:10.1021/acscentsci.7b00255 · Cited by 252
Metadata
- Authors
- Johnson, L. K., Mecking, S., & Brookhart, M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 1996-01-01
- Volume
- 118
- Issue
- 1
- Pages
- 267-268
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2004182290
- Cited by
- 1,319
- References
- 0
- FWCI
- 32.91
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Copolymerization of Ethylene and Propylene with Functionalized Vinyl Monomers by Palladium(II) Catalysts. https://app.cochat.ai/papers/10.1021/ja953247i
- The paper
- Johnson, L. K., Mecking, S., & Brookhart, M. (1996). Copolymerization of Ethylene and Propylene with Functionalized Vinyl Monomers by Palladium(II) Catalysts. Journal of the American Chemical Society. https://doi.org/10.1021/ja953247i
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
