The DOI matches its Crossref record; 22 of the 22 references it cites were found in a registry or an index.
Synthesis of Highly Branched Polyethylene Using “Sandwich” (8-p-Tolyl naphthyl α-diimine)nickel(II) Catalysts
Abstract
Nickel(II) α-diimine dibromide complexes incorporating 8- p -tolylnaphthylimino groups have been prepared and used for ethylene polymerization by activation with modified methylalumoxane (MMAO). These catalysts possess increased axial bulk relative to standard diimine-nickel complexes, resulting in lower rates of chain transfer relative to chain propagation rates and thus higher polymer molecular weights and narrower PDIs. They yield the most highly branched PE produced by Ni catalysts seen to date. The easy synthesis of 8-aryl-1-naphthylamines provides ready access to a new class of α-diimine-based nickel catalysts in which the 8-substituent is ideally positioned to provide steric bulk at the axial sites.
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Cites
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Self-citationNew Pd(II)- and Ni(II)-Based Catalysts for Polymerization of Ethylene and .alpha.-Olefins
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Self-citationAdvances in Non-Metallocene Olefin Polymerization Catalysis
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Self-citationNeutral, Single-Component Nickel (II) Polyolefin Catalysts That Tolerate Heteroatoms
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Novel olefin polymerization catalysts based on iron and cobalt
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Self-citationChain Walking: A New Strategy to Control Polymer Topology
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Cited by
Exploring Ethylene/Polar Vinyl Monomer Copolymerizations Using Ni and Pd α-Diimine Catalysts
Chen, Z., & Brookhart, M. (2018) · Accounts of Chemical Research · doi:10.1021/acs.accounts.8b00225 · Cited by 405
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Metadata
- Authors
- Zhang, D., Nadres, E. T., Brookhart, M., & Daugulis, O.
- Venue
- Organometallics
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-09-10
- Volume
- 32
- Issue
- 18
- Pages
- 5136-5143
- ISSN
- 0276-7333 (ISSN-L)
- 1520-6041
- OpenAlex
- W2037242583
- Cited by
- 261
- References
- 22
- FWCI
- 4.82
- Type
- journal article
- Language
- en
- Open access
- closed
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