The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
A General Descriptor Δ E Enables the Quantitative Development of Luminescent Materials Based on Photoinduced Electron Transfer
Abstract
Photoinduced electron transfer (PET) is one of the most important mechanisms for developing fluorescent probes and biosensors. Quantitative prediction of the quantum yields of these probes and sensors is crucial to accelerate the rational development of novel PET-based functional materials. Herein, we developed a general descriptor (Δ E ) for predicting the quantum yield of PET probes, with a threshold value of ∼0.6 eV. When Δ E < ∼0.6 eV, the quantum yield is low (mostly <2%) due to the substantial activation of PET in polar environments; when Δ E > ∼0.6 eV, the quantum yield is high because of the inhibition of PET. This simple yet effective descriptor is applicable to a wide range of fluorophores, such as BODIPY, fluorescein, rhodamine, and Si-rhodamine. This Δ E descriptor enables us not only to establish new applications for existing PET probes but also to quantitatively design novel PET-based fluorophores for wash-free bioimaging and AIEgen development.
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Aggregation-Induced Emission: Together We Shine, United We Soar!
Mei, J., Leung, N. L. C., Kwok, R. T. K., Lam, J. W. Y., & Tang, B. Z. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00263 · Cited by 8,270
Niu, G., Zheng, X., Zhao, Z., Zhang, H., Wang, J., He, X., Chen, Y., Shi, X., Ma, C., Kwok, R. T. K., et al. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b06196 · Cited by 183
Tu, Y., Liu, J., Zhang, H., Peng, Q., Lam, J. W. Y., & Tang, B. Z. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201907522 · Cited by 180
Cited by
Wang, C., Chi, W., Qiao, Q., Tan, D., Xu, Z., & Liu, X. (2021) · Chemical Society Reviews · doi:10.1039/d1cs00239b · Cited by 710
Self-citationActivity‐Based NIR Enzyme Fluorescent Probes for the Diagnosis of Tumors and Image‐Guided Surgery
Li, H., Kim, D., Yao, Q., Ge, H., Chung, J., Fan, J., Wang, J., Peng, X., & Yoon, J. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202009796 · Cited by 363
Metadata
- Authors
- Chi, W., Chen, J., Liu, W., Wang, C., Qi, Q., Qiao, Q., Tan, T. M., Xiong, K., Liu, X., Kang, K., Chang, Y.-T., Xu, Z., & Liu, X.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2020-03-17
- Volume
- 142
- Issue
- 14
- Pages
- 6777-6785
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W3012220288
- Cited by
- 230
- References
- 3
- FWCI
- 9.60
- Type
- journal article
- Language
- en
- Open access
- closed
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- Chi, W., Chen, J., Liu, W., Wang, C., Qi, Q., Qiao, Q., Tan, T. M., Xiong, K., Liu, X., Kang, K., Chang, Y.-T., Xu, Z., & Liu, X. (2020). A General Descriptor Δ E Enables the Quantitative Development of Luminescent Materials Based on Photoinduced Electron Transfer. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.0c01473
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